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The Continuum Between Hexagonal Planar and Trigonal Planar Geometries

New heterometallic hydride complexes that involve the addition of {Mg−H} and {Zn−H} bonds to group 10 transition metals (Pd, Pt) are reported. The side‐on coordination of a single {Mg−H} to Pd forms a well‐defined σ‐complex. In contrast, addition of three {Mg−H} or {Zn−H} bonds to Pd or Pt results i...

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Detalles Bibliográficos
Autores principales: Garçon, Martí, Phanopoulos, Andreas, Sackman, George A., Richardson, Christopher, White, Andrew J. P., Cooper, Richard I., Edwards, Alison J., Crimmin, Mark R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828084/
https://www.ncbi.nlm.nih.gov/pubmed/36094744
http://dx.doi.org/10.1002/anie.202211948