Intraligand Charge Transfer Enables Visible‐Light‐Mediated Nickel‐Catalyzed Cross‐Coupling Reactions

We demonstrate that several visible‐light‐mediated carbon−heteroatom cross‐coupling reactions can be carried out using a photoactive Ni(II) precatalyst that forms in situ from a nickel salt and a bipyridine ligand decorated with two carbazole groups (Ni(Czbpy)Cl(2)). The activation of this precataly...

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Detalles Bibliográficos
Autores principales: Cavedon, Cristian, Gisbertz, Sebastian, Reischauer, Susanne, Vogl, Sarah, Sperlich, Eric, Burke, John H., Wallick, Rachel F., Schrottke, Stefanie, Hsu, Wei‐Hsin, Anghileri, Lucia, Pfeifer, Yannik, Richter, Noah, Teutloff, Christian, Müller‐Werkmeister, Henrike, Cambié, Dario, Seeberger, Peter H., Vura‐Weis, Josh, van der Veen, Renske M., Thomas, Arne, Pieber, Bartholomäus
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828175/
https://www.ncbi.nlm.nih.gov/pubmed/36161982
http://dx.doi.org/10.1002/anie.202211433

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