Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.

The nickel catalyzed Suzuki–Miyaura‐type coupling of aryl sulfamates and boronic acid derivatives enabled by temperature‐controlled mechanochemistry via the development of a programmable PID‐controlled jar heater is reported. This base‐metal‐catalyzed, solvent‐free, all‐under‐air protocol was also s...

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Autores principales: Bolt, Robert R. A., Raby‐Buck, Sarah E., Ingram, Katharine, Leitch, Jamie A., Browne, Duncan L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828252/
https://www.ncbi.nlm.nih.gov/pubmed/36082766
http://dx.doi.org/10.1002/anie.202210508
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author Bolt, Robert R. A.
Raby‐Buck, Sarah E.
Ingram, Katharine
Leitch, Jamie A.
Browne, Duncan L.
author_facet Bolt, Robert R. A.
Raby‐Buck, Sarah E.
Ingram, Katharine
Leitch, Jamie A.
Browne, Duncan L.
author_sort Bolt, Robert R. A.
collection PubMed
description The nickel catalyzed Suzuki–Miyaura‐type coupling of aryl sulfamates and boronic acid derivatives enabled by temperature‐controlled mechanochemistry via the development of a programmable PID‐controlled jar heater is reported. This base‐metal‐catalyzed, solvent‐free, all‐under‐air protocol was also scaled 200‐fold using twin‐screw extrusion technology affording decagram quantities of material.[Image: see text]
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spelling pubmed-98282522023-01-10 Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion. Bolt, Robert R. A. Raby‐Buck, Sarah E. Ingram, Katharine Leitch, Jamie A. Browne, Duncan L. Angew Chem Int Ed Engl Research Articles The nickel catalyzed Suzuki–Miyaura‐type coupling of aryl sulfamates and boronic acid derivatives enabled by temperature‐controlled mechanochemistry via the development of a programmable PID‐controlled jar heater is reported. This base‐metal‐catalyzed, solvent‐free, all‐under‐air protocol was also scaled 200‐fold using twin‐screw extrusion technology affording decagram quantities of material.[Image: see text] John Wiley and Sons Inc. 2022-10-05 2022-11-02 /pmc/articles/PMC9828252/ /pubmed/36082766 http://dx.doi.org/10.1002/anie.202210508 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by/4.0/ (https://creativecommons.org/licenses/by/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited.
spellingShingle Research Articles
Bolt, Robert R. A.
Raby‐Buck, Sarah E.
Ingram, Katharine
Leitch, Jamie A.
Browne, Duncan L.
Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title_full Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title_fullStr Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title_full_unstemmed Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title_short Temperature‐Controlled Mechanochemistry for the Nickel‐Catalyzed Suzuki–Miyaura‐Type Coupling of Aryl Sulfamates via Ball Milling and Twin‐Screw Extrusion.
title_sort temperature‐controlled mechanochemistry for the nickel‐catalyzed suzuki–miyaura‐type coupling of aryl sulfamates via ball milling and twin‐screw extrusion.
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828252/
https://www.ncbi.nlm.nih.gov/pubmed/36082766
http://dx.doi.org/10.1002/anie.202210508
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