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Terpyridine Diphosphine Ruthenium Complexes as Efficient Photocatalysts for the Transfer Hydrogenation of Carbonyl Compounds

The cationic achiral and chiral terpyridine diphosphine ruthenium complexes [RuCl(PP)(tpy)]Cl (PP=dppp (1), (R,R)‐Skewphos (2) and (S,S)‐Skewphos (3)) are easily obtained in 85–88 % yield through a one‐pot synthesis from [RuCl(2)(PPh(3))(3)], the diphosphine and 2,2′:6′,2′′‐terpyridine (tpy) in 1‐bu...

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Detalles Bibliográficos
Autores principales: Ballico, Maurizio, Alessi, Dario, Jandl, Christian, Lovison, Denise, Baratta, Walter
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828271/
https://www.ncbi.nlm.nih.gov/pubmed/36001351
http://dx.doi.org/10.1002/chem.202201722

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