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Total Syntheses of (±)‐Dracocephalone A and (±)‐Dracocequinones A and B

Described herein are the first total syntheses of (±)‐dracocephalone A (1) and (±)‐dracocequinones A (4) and B (5). The synthesis was initially envisioned as proceeding through an intramolecular isobenzofuran Diels–Alder reaction, a strategy that eventually evolved into a Lewis acid‐promoted spirocy...

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Detalles Bibliográficos
Autores principales: Hwang, Taehwan, Tuccinardi, Joseph P., Beard, Alexandra A., Jackson, Amy C., Jung, Min J., Wood, John L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828498/
https://www.ncbi.nlm.nih.gov/pubmed/36121442
http://dx.doi.org/10.1002/anie.202210821

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