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Full Control of the Chiral Overpass Effect in Helical Polymers: P/M Screw Sense Induction by Remote Chiral Centers After Bypassing the First Chiral Residue

In helical polymers, helical sense induction is usually commanded by teleinduction mechanism, where the largest substituent of the chiral residue directly attached to the main chain is the one that commands the helical sense. In this work, different helical structures with different helical senses a...

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Detalles Bibliográficos
Autores principales: Rodríguez, Rafael, Rivadulla‐Cendal, Elena, Fernández‐Míguez, Manuel, Fernández, Berta, Maeda, Katsuhiro, Quiñoá, Emilio, Freire, Félix
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828504/
https://www.ncbi.nlm.nih.gov/pubmed/36121741
http://dx.doi.org/10.1002/anie.202209953