Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)

PhI(OTf)(2) and related ArI(OTf)(2) species have been incorrectly invoked as intermediates in oxidation reactions for many years. We recently established that such compounds did not yet exist but remain an attractive target. Here we describe the synthesis, isolation, and structural characterization...

Descripción completa

Detalles Bibliográficos
Autores principales: Sharp‐Bucknall, Lachlan, Tania, Dutton, Jason L.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828558/
https://www.ncbi.nlm.nih.gov/pubmed/36104294
http://dx.doi.org/10.1002/anie.202212380
_version_ 1784867301112152064
author Sharp‐Bucknall, Lachlan
Tania,
Dutton, Jason L.
author_facet Sharp‐Bucknall, Lachlan
Tania,
Dutton, Jason L.
author_sort Sharp‐Bucknall, Lachlan
collection PubMed
description PhI(OTf)(2) and related ArI(OTf)(2) species have been incorrectly invoked as intermediates in oxidation reactions for many years. We recently established that such compounds did not yet exist but remain an attractive target. Here we describe the synthesis, isolation, and structural characterization of NO(2)‐PhI(OTf)(2,) which is resistant to decomposition and more reactive than PhI(OTf)(OAc), the species previously misidentified as PhI(OTf)(2).
format Online
Article
Text
id pubmed-9828558
institution National Center for Biotechnology Information
language English
publishDate 2022
publisher John Wiley and Sons Inc.
record_format MEDLINE/PubMed
spelling pubmed-98285582023-01-10 Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2) Sharp‐Bucknall, Lachlan Tania, Dutton, Jason L. Angew Chem Int Ed Engl Communications PhI(OTf)(2) and related ArI(OTf)(2) species have been incorrectly invoked as intermediates in oxidation reactions for many years. We recently established that such compounds did not yet exist but remain an attractive target. Here we describe the synthesis, isolation, and structural characterization of NO(2)‐PhI(OTf)(2,) which is resistant to decomposition and more reactive than PhI(OTf)(OAc), the species previously misidentified as PhI(OTf)(2). John Wiley and Sons Inc. 2022-10-17 2022-11-14 /pmc/articles/PMC9828558/ /pubmed/36104294 http://dx.doi.org/10.1002/anie.202212380 Text en © 2022 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc/4.0/ (https://creativecommons.org/licenses/by-nc/4.0/) License, which permits use, distribution and reproduction in any medium, provided the original work is properly cited and is not used for commercial purposes.
spellingShingle Communications
Sharp‐Bucknall, Lachlan
Tania,
Dutton, Jason L.
Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title_full Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title_fullStr Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title_full_unstemmed Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title_short Synthesis and Structural Verification of an ArI(OTf)(2), NO(2)‐Ph‐I(OTf)(2)
title_sort synthesis and structural verification of an ari(otf)(2), no(2)‐ph‐i(otf)(2)
topic Communications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828558/
https://www.ncbi.nlm.nih.gov/pubmed/36104294
http://dx.doi.org/10.1002/anie.202212380
work_keys_str_mv AT sharpbucknalllachlan synthesisandstructuralverificationofanariotf2no2phiotf2
AT tania synthesisandstructuralverificationofanariotf2no2phiotf2
AT duttonjasonl synthesisandstructuralverificationofanariotf2no2phiotf2

Ejemplares similares