Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation

Borate buffer was found to have both structural and functional roles within a low‐cost tri‐copper electrocatalyst for homogeneous water oxidation that exhibits a high turnover frequency of 310 s(−1). The borate buffer was shown to facilitate the catalytic activity by both bridging the three Cu ions...

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Detalles Bibliográficos
Autores principales: Ruan, Guilin, Fridman, Natalia, Maayan, Galia
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828671/
https://www.ncbi.nlm.nih.gov/pubmed/36040755
http://dx.doi.org/10.1002/chem.202202407
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author Ruan, Guilin
Fridman, Natalia
Maayan, Galia
author_facet Ruan, Guilin
Fridman, Natalia
Maayan, Galia
author_sort Ruan, Guilin
collection PubMed
description Borate buffer was found to have both structural and functional roles within a low‐cost tri‐copper electrocatalyst for homogeneous water oxidation that exhibits a high turnover frequency of 310 s(−1). The borate buffer was shown to facilitate the catalytic activity by both bridging the three Cu ions and participating in O−O bond formation. Phosphate and acetate buffers did not show such roles, making borate a unique player in this catalytic system.
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spelling pubmed-98286712023-01-10 Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation Ruan, Guilin Fridman, Natalia Maayan, Galia Chemistry Research Articles Borate buffer was found to have both structural and functional roles within a low‐cost tri‐copper electrocatalyst for homogeneous water oxidation that exhibits a high turnover frequency of 310 s(−1). The borate buffer was shown to facilitate the catalytic activity by both bridging the three Cu ions and participating in O−O bond formation. Phosphate and acetate buffers did not show such roles, making borate a unique player in this catalytic system. John Wiley and Sons Inc. 2022-09-26 2022-11-25 /pmc/articles/PMC9828671/ /pubmed/36040755 http://dx.doi.org/10.1002/chem.202202407 Text en © 2022 The Authors. Chemistry - A European Journal published by Wiley-VCH GmbH https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the terms of the http://creativecommons.org/licenses/by-nc-nd/4.0/ (https://creativecommons.org/licenses/by-nc-nd/4.0/) License, which permits use and distribution in any medium, provided the original work is properly cited, the use is non‐commercial and no modifications or adaptations are made.
spellingShingle Research Articles
Ruan, Guilin
Fridman, Natalia
Maayan, Galia
Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title_full Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title_fullStr Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title_full_unstemmed Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title_short Borate Buffer as a Key Player in Cu‐Based Homogeneous Electrocatalytic Water Oxidation
title_sort borate buffer as a key player in cu‐based homogeneous electrocatalytic water oxidation
topic Research Articles
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828671/
https://www.ncbi.nlm.nih.gov/pubmed/36040755
http://dx.doi.org/10.1002/chem.202202407
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AT maayangalia boratebufferasakeyplayerincubasedhomogeneouselectrocatalyticwateroxidation

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