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A Germapyramidane Switches Between 3D Cluster and 2D Cyclic Structures in Single‐Electron Steps

Reaction of the imidazolium‐substituted iphosphate‐diide, (Ipr)(2)C(2)P(2) (IDP), with GeCl(2) ⋅ dioxane and KBArF(24) [(BarF(24))(−)=tetrakis[(3,5‐trifluoromethyl)phenyl]borate)] afforded the dicationic spherical‐aromatic nido‐cluster [Ge(η(4)‐IDP)](2+) ([1](2+)) (Ipr=1,3‐bis(2,6‐diisopropylphenyl)...

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Detalles Bibliográficos
Autores principales:	Coburger, Peter, Masero, Fabio, Bösken, Jonas, Mougel, Victor, Grützmacher, Hansjörg
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Research Articles
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828763/ https://www.ncbi.nlm.nih.gov/pubmed/36152009 http://dx.doi.org/10.1002/anie.202211749

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