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Dearomative (3+2) Cycloadditions between Indoles and Vinyldiazo Species Enabled by a Red‐Shifted Chromium Photocatalyst

A direct dearomative photocatalyzed (3+2) cycloaddition between indoles and vinyldiazo reagents is described. The transformation is enabled by the development of a novel oxidizing Cr(III) photocatalyst, its specific reactivity attributed to increased absorptive properties over earlier Cr analogs and...

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Detalles Bibliográficos
Autores principales: Gall, Bradley K., Smith, Avery K., Ferreira, Eric M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9828771/
https://www.ncbi.nlm.nih.gov/pubmed/36063422
http://dx.doi.org/10.1002/anie.202212187

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