Etching-Induced Surface Reconstruction of NiMoO(4) for Oxygen Evolution Reaction

Rational reconstruction of oxygen evolution reaction (OER) pre-catalysts and performance index of OER catalysts are crucial but still challenging for universal water electrolysis. Herein, we develop a double-cation etching strategy to tailor the electronic structure of NiMoO(4), where the prepared NiMoO(4) nanorods etched by H(2)O(2) reconstruct their surface with abundant cation deficiencies and lattice distortion. Calculation results reveal that the double cation deficiencies can make the upshift of d-band center for Ni atoms and the active sites with better oxygen adsorption capacity. As a result, the optimized sample (NMO-30M) possesses an overpotential of 260 mV at 10 mA cm(−2) and excellent long-term durability of 162 h. Importantly, in situ Raman test reveals the rapid formation of high-oxidation-state transition metal hydroxide species, which can further help to improve the catalytic activity of NiMoO(4) in OER. This work highlights the influence of surface remodification and shed some light on activating catalysts. [Image: see text] SUPPLEMENTARY INFORMATION: The online version contains supplementary material available at 10.1007/s40820-022-01011-3.