Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity

Herein, novel nano-sized 1,1-diamino-2,2-dinitroethylene (C(2)H(4)N(4)O(4), FOX-7)/zeolitic imidazolate framework-8 (ZIF-8) composites are constructed by facile liquid-assisted mechanochemical reactions. In contrast to two-step thermal decomposition of raw FOX-7, the prepared FOX-7/ZIF-8 composites...

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Detalles Bibliográficos
Autores principales: Wang, Binshen, Jiao, Fangbao, Xu, Rong, Li, Hongzhen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9830530/
https://www.ncbi.nlm.nih.gov/pubmed/36712649
http://dx.doi.org/10.1039/d2ra06783h
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author Wang, Binshen
Jiao, Fangbao
Xu, Rong
Li, Hongzhen
author_facet Wang, Binshen
Jiao, Fangbao
Xu, Rong
Li, Hongzhen
author_sort Wang, Binshen
collection PubMed
description Herein, novel nano-sized 1,1-diamino-2,2-dinitroethylene (C(2)H(4)N(4)O(4), FOX-7)/zeolitic imidazolate framework-8 (ZIF-8) composites are constructed by facile liquid-assisted mechanochemical reactions. In contrast to two-step thermal decomposition of raw FOX-7, the prepared FOX-7/ZIF-8 composites demonstrate a single high-intensity exothermal decomposition attributed to the catalysis of ZIF-8. Benefiting from nano-sized energetic materials and the buffering effect of ZIF-8, the mechanical sensitives of FOX-7/ZIF-8 composites are decreased.
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spelling pubmed-98305302023-01-26 Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity Wang, Binshen Jiao, Fangbao Xu, Rong Li, Hongzhen RSC Adv Chemistry Herein, novel nano-sized 1,1-diamino-2,2-dinitroethylene (C(2)H(4)N(4)O(4), FOX-7)/zeolitic imidazolate framework-8 (ZIF-8) composites are constructed by facile liquid-assisted mechanochemical reactions. In contrast to two-step thermal decomposition of raw FOX-7, the prepared FOX-7/ZIF-8 composites demonstrate a single high-intensity exothermal decomposition attributed to the catalysis of ZIF-8. Benefiting from nano-sized energetic materials and the buffering effect of ZIF-8, the mechanical sensitives of FOX-7/ZIF-8 composites are decreased. The Royal Society of Chemistry 2023-01-10 /pmc/articles/PMC9830530/ /pubmed/36712649 http://dx.doi.org/10.1039/d2ra06783h Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Binshen
Jiao, Fangbao
Xu, Rong
Li, Hongzhen
Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title_full Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title_fullStr Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title_full_unstemmed Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title_short Construction of nano-sized FOX-7/ZIF-8 composites for fast decomposition and reduced sensitivity
title_sort construction of nano-sized fox-7/zif-8 composites for fast decomposition and reduced sensitivity
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9830530/
https://www.ncbi.nlm.nih.gov/pubmed/36712649
http://dx.doi.org/10.1039/d2ra06783h
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AT jiaofangbao constructionofnanosizedfox7zif8compositesforfastdecompositionandreducedsensitivity
AT xurong constructionofnanosizedfox7zif8compositesforfastdecompositionandreducedsensitivity
AT lihongzhen constructionofnanosizedfox7zif8compositesforfastdecompositionandreducedsensitivity

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