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Chemical bonding and dynamic structural fluxionality of a boron-based Al(2)B(8) binary cluster: the robustness of a doubly 6π/6σ aromatic [B(8)](2−) molecular wheel
Despite the isovalency between Al and B elements, Al-doping in boron clusters can deviate substantially from an isoelectronic substitution process. We report herein on a unique sandwich di-Al-doped boron cluster, Al(2)B(8), using global structural searches and quantum chemical calculations. The clus...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2023
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9833104/ https://www.ncbi.nlm.nih.gov/pubmed/36712639 http://dx.doi.org/10.1039/d2ra07268h |