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Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars

We report a huge organic diversity in the Tissint Mars meteorite and the sampling of several mineralogical lithologies, which revealed that the organic molecules were nonuniformly distributed in functionality and abundance. The range of organics in Tissint meteorite were abundant C(3-7) aliphatic br...

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Autores principales: Schmitt-Kopplin, Philippe, Matzka, Marco, Ruf, Alexander, Menez, Benedicte, Chennaoui Aoudjehane, Hasnaa, Harir, Mourad, Lucio, Marianna, Hertzog, Jasmine, Hertkorn, Norbert, Gougeon, Régis D., Hoffmann, Victor, Hinman, Nancy W., Ferrière, Ludovic, Greshake, Ansgar, Gabelica, Zelimir, Trif, László, Steele, Andrew
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Association for the Advancement of Science 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9833655/
https://www.ncbi.nlm.nih.gov/pubmed/36630504
http://dx.doi.org/10.1126/sciadv.add6439
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author Schmitt-Kopplin, Philippe
Matzka, Marco
Ruf, Alexander
Menez, Benedicte
Chennaoui Aoudjehane, Hasnaa
Harir, Mourad
Lucio, Marianna
Hertzog, Jasmine
Hertkorn, Norbert
Gougeon, Régis D.
Hoffmann, Victor
Hinman, Nancy W.
Ferrière, Ludovic
Greshake, Ansgar
Gabelica, Zelimir
Trif, László
Steele, Andrew
author_facet Schmitt-Kopplin, Philippe
Matzka, Marco
Ruf, Alexander
Menez, Benedicte
Chennaoui Aoudjehane, Hasnaa
Harir, Mourad
Lucio, Marianna
Hertzog, Jasmine
Hertkorn, Norbert
Gougeon, Régis D.
Hoffmann, Victor
Hinman, Nancy W.
Ferrière, Ludovic
Greshake, Ansgar
Gabelica, Zelimir
Trif, László
Steele, Andrew
author_sort Schmitt-Kopplin, Philippe
collection PubMed
description We report a huge organic diversity in the Tissint Mars meteorite and the sampling of several mineralogical lithologies, which revealed that the organic molecules were nonuniformly distributed in functionality and abundance. The range of organics in Tissint meteorite were abundant C(3-7) aliphatic branched carboxylic acids and aldehydes, olefins, and polyaromatics with and without heteroatoms in a homologous oxidation structural continuum. Organomagnesium compounds were extremely abundant in olivine macrocrystals and in the melt veins, reflecting specific organo-synsthesis processes in close interaction with the magnesium silicates and temperature stresses, as previously observed. The diverse chemistry and abundance in complex molecules reveal heterogeneity in organic speciation within the minerals grown in the martian mantle and crust that may have evolved over geological time.
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spelling pubmed-98336552023-01-18 Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars Schmitt-Kopplin, Philippe Matzka, Marco Ruf, Alexander Menez, Benedicte Chennaoui Aoudjehane, Hasnaa Harir, Mourad Lucio, Marianna Hertzog, Jasmine Hertkorn, Norbert Gougeon, Régis D. Hoffmann, Victor Hinman, Nancy W. Ferrière, Ludovic Greshake, Ansgar Gabelica, Zelimir Trif, László Steele, Andrew Sci Adv Earth, Environmental, Ecological, and Space Sciences We report a huge organic diversity in the Tissint Mars meteorite and the sampling of several mineralogical lithologies, which revealed that the organic molecules were nonuniformly distributed in functionality and abundance. The range of organics in Tissint meteorite were abundant C(3-7) aliphatic branched carboxylic acids and aldehydes, olefins, and polyaromatics with and without heteroatoms in a homologous oxidation structural continuum. Organomagnesium compounds were extremely abundant in olivine macrocrystals and in the melt veins, reflecting specific organo-synsthesis processes in close interaction with the magnesium silicates and temperature stresses, as previously observed. The diverse chemistry and abundance in complex molecules reveal heterogeneity in organic speciation within the minerals grown in the martian mantle and crust that may have evolved over geological time. American Association for the Advancement of Science 2023-01-11 /pmc/articles/PMC9833655/ /pubmed/36630504 http://dx.doi.org/10.1126/sciadv.add6439 Text en Copyright © 2023 The Authors, some rights reserved; exclusive licensee American Association for the Advancement of Science. No claim to original U.S. Government Works. Distributed under a Creative Commons Attribution NonCommercial License 4.0 (CC BY-NC). https://creativecommons.org/licenses/by-nc/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution-NonCommercial license (https://creativecommons.org/licenses/by-nc/4.0/) , which permits use, distribution, and reproduction in any medium, so long as the resultant use is not for commercial advantage and provided the original work is properly cited.
spellingShingle Earth, Environmental, Ecological, and Space Sciences
Schmitt-Kopplin, Philippe
Matzka, Marco
Ruf, Alexander
Menez, Benedicte
Chennaoui Aoudjehane, Hasnaa
Harir, Mourad
Lucio, Marianna
Hertzog, Jasmine
Hertkorn, Norbert
Gougeon, Régis D.
Hoffmann, Victor
Hinman, Nancy W.
Ferrière, Ludovic
Greshake, Ansgar
Gabelica, Zelimir
Trif, László
Steele, Andrew
Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title_full Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title_fullStr Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title_full_unstemmed Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title_short Complex carbonaceous matter in Tissint martian meteorites give insights into the diversity of organic geochemistry on Mars
title_sort complex carbonaceous matter in tissint martian meteorites give insights into the diversity of organic geochemistry on mars
topic Earth, Environmental, Ecological, and Space Sciences
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9833655/
https://www.ncbi.nlm.nih.gov/pubmed/36630504
http://dx.doi.org/10.1126/sciadv.add6439
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