Influence of Highly Stable Ni(2+) Species in Ni Phyllosilicate Catalysts on Selective Hydrogenation of Furfural to Furfuryl Alcohol

[Image: see text] Enhancing the catalytic performance of non-noble Ni catalysts in the selective hydrogenation of furfural to furfuryl alcohol (FA) in terms of furfural conversion, selectivity, and good recyclability is challenging. Here, spherical nickel phyllosilicate catalysts (Ni_PS) with fibrous-like structures are prepared via a modified sol–gel method with Ni loadings of 2–30 wt %. Upon exposure to air, all the reduced Ni_PS catalysts exhibit more than 80% Ni(0)/Ni(phyllosilicate) species on the surface, whereas a large portion of Ni oxide species (>55%) is presented on the impregnated catalyst. The Ni(2+) species in nickel phyllosilicate catalysts are active and highly stable during reduction, reaction, and regeneration, yielding stable catalytic performance for multiple recycle tests in furfural hydrogenation to FA. Furfural conversion over the Ni_PS catalysts increased monotonically with increasing Ni loading without an FA selectivity drop. The presence of both metallic Ni(0) and Ni(phyllosilicate) also produces a synergistic promotional effect for FA formation.