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α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation

[Image: see text] The ever-expanding human societies on the one hand and the diminishing fossil fuel resources on the other have driven man to find a suitable, cheap, clean, and accessible source of energy. Water splitting is a good solution to this crisis. Because of the slow kinetics of water oxid...

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Autores principales: Shahparast, Saeedeh, Asadpour-Zeynali, Karim
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9835177/
https://www.ncbi.nlm.nih.gov/pubmed/36643503
http://dx.doi.org/10.1021/acsomega.2c07580
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author Shahparast, Saeedeh
Asadpour-Zeynali, Karim
author_facet Shahparast, Saeedeh
Asadpour-Zeynali, Karim
author_sort Shahparast, Saeedeh
collection PubMed
description [Image: see text] The ever-expanding human societies on the one hand and the diminishing fossil fuel resources on the other have driven man to find a suitable, cheap, clean, and accessible source of energy. Water splitting is a good solution to this crisis. Because of the slow kinetics of water oxidation reaction, it is important to select efficient and durable electrocatalysts to improve the reaction kinetics. In this research, α-MnO(2)/FeCo-LDH catalysts on nickel foam were developed for water oxidation, which exhibited good catalytic performance and stability in a 0.1 M KOH solution. The electrocatalysts were synthesized by hydrothermal methods and characterized by XRD, FTIR, Raman, SEM, TEM, EDS, and MAP techniques. The proposed modified electrode has large exchange current, low overpotential, and small Tafel slope. Here, only an overpotential of 210 mV is required to achieve a current density of 5 mA cm(2) with a Tafel slope of 70.4 mV dec(–1) in an alkaline solution.
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spelling pubmed-98351772023-01-13 α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation Shahparast, Saeedeh Asadpour-Zeynali, Karim ACS Omega [Image: see text] The ever-expanding human societies on the one hand and the diminishing fossil fuel resources on the other have driven man to find a suitable, cheap, clean, and accessible source of energy. Water splitting is a good solution to this crisis. Because of the slow kinetics of water oxidation reaction, it is important to select efficient and durable electrocatalysts to improve the reaction kinetics. In this research, α-MnO(2)/FeCo-LDH catalysts on nickel foam were developed for water oxidation, which exhibited good catalytic performance and stability in a 0.1 M KOH solution. The electrocatalysts were synthesized by hydrothermal methods and characterized by XRD, FTIR, Raman, SEM, TEM, EDS, and MAP techniques. The proposed modified electrode has large exchange current, low overpotential, and small Tafel slope. Here, only an overpotential of 210 mV is required to achieve a current density of 5 mA cm(2) with a Tafel slope of 70.4 mV dec(–1) in an alkaline solution. American Chemical Society 2022-12-20 /pmc/articles/PMC9835177/ /pubmed/36643503 http://dx.doi.org/10.1021/acsomega.2c07580 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Shahparast, Saeedeh
Asadpour-Zeynali, Karim
α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title_full α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title_fullStr α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title_full_unstemmed α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title_short α-MnO(2)/FeCo-LDH on Nickel Foam as an Efficient Electrocatalyst for Water Oxidation
title_sort α-mno(2)/feco-ldh on nickel foam as an efficient electrocatalyst for water oxidation
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9835177/
https://www.ncbi.nlm.nih.gov/pubmed/36643503
http://dx.doi.org/10.1021/acsomega.2c07580
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