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Cyclic Diaryl λ(3)-Chloranes: Reagents and Their C–C and C–O Couplings with Phenols via Aryne Intermediates

[Image: see text] Hypervalent chloranes are a class of rare and poorly explored reagents. Their unique electronic properties confer reactivity that is complementary to that of the common iodanes and emerging bromanes. Highly chemo- and regioselective, metal-free, and mild C–C and C–O couplings are r...

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Detalles Bibliográficos
Autores principales: Lanzi, Matteo, Rogge, Torben, Truong, Tan Sang, Houk, K. N., Wencel-Delord, Joanna
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837845/
https://www.ncbi.nlm.nih.gov/pubmed/36535642
http://dx.doi.org/10.1021/jacs.2c10090