Cargando…

Iridium-Catalyzed Double Convergent 1,3-Rearrangement/Hydrogenation of Allylic Alcohols

[Image: see text] Enantioconvergent catalysis has the potential to convert different isomers of a starting material to a single highly enantioenriched product. Here we report a novel enantioselective double convergent 1,3-rearrangement/hydrogenation of allylic alcohols using an Ir-N,P catalyst. A va...

Descripción completa

Detalles Bibliográficos
Autores principales:	Yang, Jianping, Massaro, Luca, Hu, Weigao, Peters, Bram B. C., Birke, Norman, Chantana, Chayamon, Singh, Thishana, Andersson, Pher G.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	American Chemical Society 2022
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9837846/ https://www.ncbi.nlm.nih.gov/pubmed/36534479 http://dx.doi.org/10.1021/jacs.2c11289

Ejemplares similares

Iridium-catalyzed enantioconvergent hydrogenation of trisubstituted olefins
por: Peters, Bram B. C., et al.
Publicado: (2022)

Kinetic resolution of racemic allylic alcohols via iridium-catalyzed asymmetric hydrogenation: scope, synthetic applications and insight into the origin of selectivity
por: Wu, Haibo, et al.
Publicado: (2020)

Asymmetric synthesis of 1,2-fluorohydrin: iridium catalyzed hydrogenation of fluorinated allylic alcohol
por: Ponra, Sudipta, et al.
Publicado: (2020)

Site‐ and Enantioselective Iridium‐Catalyzed Desymmetric Mono‐Hydrogenation of 1,4‐Dienes
por: Wu, Haibo, et al.
Publicado: (2021)

Highly Enantioselective Iridium-Catalyzed Hydrogenation of Conjugated Trisubstituted Enones
por: Peters, Bram B. C., et al.
Publicado: (2020)

Stereoselective Iridium-N,P-Catalyzed Double Hydrogenation of Conjugated Enones to Saturated Alcohols
por: Peters, Bram B. C., et al.
Publicado: (2022)

Synthesis of Chiral Tetrahydro-3-benzazepine Motifs by Iridium-Catalyzed Asymmetric Hydrogenation of Cyclic Ene-carbamates
por: Peters, Bram B. C., et al.
Publicado: (2022)

Iridium-Catalyzed 1,3-Hydrogen Shift/Chlorination of Allylic Alcohols**
por: Ahlsten, Nanna, et al.
Publicado: (2013)

Combined Theoretical and Experimental Studies Unravel Multiple Pathways to Convergent Asymmetric Hydrogenation of Enamides
por: Yang, Jianping, et al.
Publicado: (2021)

Cationic NHC‐Phosphine Iridium Complexes: Highly Active Catalysts for Base‐Free Hydrogenation of Ketones
por: Quan, Xu, et al.
Publicado: (2020)

Iridium-catalyzed enantioselective direct vinylogous allylic alkylation of coumarins
por: Sarkar, Rahul, et al.
Publicado: (2018)

Iridium‐Catalyzed Enantioselective Intermolecular Indole C2‐Allylation
por: Rossi‐Ashton, James A., et al.
Publicado: (2020)

Catalytic enantioselective synthesis of fluoromethylated stereocenters by asymmetric hydrogenation
por: Yang, Jianping, et al.
Publicado: (2022)

Iridium-catalyzed enantioselective alkynylation and kinetic resolution of alkyl allylic alcohols
por: Guo, Jia, et al.
Publicado: (2022)

Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
por: Sarkar, Rahul, et al.
Publicado: (2021)

Stereodivergent synthesis via iridium-catalyzed asymmetric double allylic alkylation of cyanoacetate
por: Shen, Chong, et al.
Publicado: (2021)

Enantioselective construction of C-chiral allylic sulfilimines via the iridium-catalyzed allylic amination with S,S-diphenylsulfilimine: asymmetric synthesis of primary allylic amines
por: Grange, Rebecca L., et al.
Publicado: (2015)

Tandem Peterson olefination and chemoselective asymmetric hydrogenation of β-hydroxy silanes
por: Krajangsri, Suppachai, et al.
Publicado: (2019)

The Implications of the Brønsted Acidic Properties of Crabtree-Type Catalysts in the Asymmetric Hydrogenation of Olefins
por: Peters, Bram B. C., et al.
Publicado: (2022)

Z-Selective iridium-catalyzed cross-coupling of allylic carbonates and α-diazo esters
por: Thomas, Bryce N., et al.
Publicado: (2017)

Correction: Iridium-catalyzed enantioselective olefinic C(sp(2))–H allylic alkylation
por: Sarkar, Rahul, et al.
Publicado: (2021)

Development of Immobilized Carreira (Phosphoramidite, Olefin) Ligands and Application in Iridium-Catalyzed Asymmetric Allylic Amination
por: Zhou, Leijie, et al.
Publicado: (2023)

A Tandem Iridium-Catalyzed “Chain-Walking”/Cope Rearrangement Sequence
por: Sommer, Heiko, et al.
Publicado: (2019)

Preparation of Butadienylpyridines by Iridium‐NHC‐Catalyzed Alkyne Hydroalkenylation and Quinolizine Rearrangement
por: Azpíroz, Ramón, et al.
Publicado: (2021)

Highly Enantioselective Iridium‐Catalyzed Hydrogenation of Cyclic Enamides
por: Salomó, Ernest, et al.
Publicado: (2016)

Iridium-catalyzed asymmetric trans-selective hydrogenation of 1,3-disubstituted isoquinolines
por: Kim, Alexia N., et al.
Publicado: (2022)

Diastereo- and Enantioselective Iridium-Catalyzed Allylation of Cyclic Ketone Enolates: Synergetic Effect of Ligands and Barium Enolates
por: Chen, Wenyong, et al.
Publicado: (2014)

Gold-catalyzed intermolecular coupling of sulfonylacetylene with allyl ethers: [3,3]- and [1,3]-rearrangements
por: Jun, Jungho, et al.
Publicado: (2013)

Hydrogen-Borrowing and Interrupted-Hydrogen-Borrowing Reactions of Ketones and Methanol Catalyzed by Iridium**
por: Shen, Di, et al.
Publicado: (2015)

Asymmetric Full Saturation of Vinylarenes with Cooperative Homogeneous and Heterogeneous Rhodium Catalysis
por: Wu, Haibo, et al.
Publicado: (2021)

Tungsten-Catalyzed Asymmetric Epoxidation of Allylic and Homoallylic Alcohols with Hydrogen Peroxide
por: Wang, Chuan, et al.
Publicado: (2014)

Chirality memory of α-methylene-π-allyl iridium species
por: Cui, Yifan, et al.
Publicado: (2021)

Application of Phosphine-Phosphite Ligands in the Iridium Catalyzed Enantioselective Hydrogenation of 2-Methylquinoline
por: Rubio, Miguel, et al.
Publicado: (2010)

Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols
por: Yang, Xiao-Hui, et al.
Publicado: (2017)

A Vinyl Cyclopropane Ring Expansion and Iridium‐Catalyzed Hydrogen Borrowing Cascade
por: Wübbolt, Simon, et al.
Publicado: (2020)

Iridium Complex-Catalyzed Transfer Hydrogenation of N-Heteroarenes and Tentative Asymmetric Synthesis
por: Ouyang, Lu, et al.
Publicado: (2021)

Iridium‐Catalyzed Domino Hydroformylation/Hydrogenation of Olefins to Alcohols: Synergy of Two Ligands
por: Huang, Weiheng, et al.
Publicado: (2022)

Gold(I)-catalyzed formation of furans by a Claisen-type rearrangement of ynenyl allyl ethers
por: Istrate, Florin M, et al.
Publicado: (2011)

Palladium-Catalyzed Cascade Wacker/Allylation Sequence with Allylic Alcohols Leading to Allylated Dihydropyrones
por: Huang, Wen-Yu, et al.
Publicado: (2017)

Copper-Catalyzed Enantioselective Borylative Allyl–Allyl Coupling of Allenes and Allylic gem-Dichlorides
por: Piñeiro-Suárez, Martín, et al.
Publicado: (2023)

Cannot write session to /tmp/vufind_sessions/sess_e8vms3eb51fsvoa1f50gvbks1m