Monitoring Ozone Using Portable Substrate-Integrated Hollow Waveguide-Based Absorbance Sensors in the Ultraviolet Range

[Image: see text] Ozone is an oxidizing molecule used for disinfecting a wide variety of environments, such as in dental clinics, and has most recently been promoted as a sanitizing agent to prevent coronavirus transmission. The easy access to ozone-generating sources also enables their ubiquitous use. However, exposure to ozone may seriously affect human health by amplifying or inducing respiratory diseases and distress syndromes and has been associated with premature deaths from other diseases. In this scenario, miniaturized, low-cost, and portable optical sensors based on the absorption signature of ozone in the ultraviolet (UV) range of the electromagnetic spectrum are an innovative approach for providing real-time monitoring of gaseous ozone, ensuring the safety of indoor and workplace environments. In this paper, a miniaturized ozone sensor based on the absorption signature of ozone at deep-UV frequencies was developed by integration of so-called substrate-integrated hollow waveguides (iHWG) with a miniaturized ultraviolet lamp and a fiber-optic USB-connected spectrophotometer. The innovative concept of iHWGs facilitates unprecedented compact dimensions with a high degree of flexibility in the optical design of the actual photon absorption path. The proposed device rapidly responded to the presence of ozone (<1 min) and revealed a suitable linearity (r(2) > 0.99) in the evaluated concentration range. The limit of detection was determined at 29.4 ppbv, which renders the device suitable for measurements in the threshold range of the main regulatory agencies. Given the adaptability and modularity of this platform, we anticipate the application of this innovative concept to be equally suitable for the in situ and real-time analysis of other relevant gases providing suitable UV absorption signatures.