Stable Monoareno-pentalenes with Two Olefinic Protons

[Image: see text] A novel class of stable monoareno-pentalenes is introduced that have an olefinic proton on each five-membered ring of the pentalene subunit. Their synthesis was accomplished via a regioselective carbopalladation cascade reaction between ortho-arylacetyleno gem-dibromoolefins and TI...

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Autores principales: Mayer, Péter J., London, Gábor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841605/
https://www.ncbi.nlm.nih.gov/pubmed/36576234
http://dx.doi.org/10.1021/acs.orglett.2c03752
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author Mayer, Péter J.
London, Gábor
author_facet Mayer, Péter J.
London, Gábor
author_sort Mayer, Péter J.
collection PubMed
description [Image: see text] A novel class of stable monoareno-pentalenes is introduced that have an olefinic proton on each five-membered ring of the pentalene subunit. Their synthesis was accomplished via a regioselective carbopalladation cascade reaction between ortho-arylacetyleno gem-dibromoolefins and TIPS-acetylene. These molecules could be experimental probes of magnetic (anti)aromaticity effects.
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spelling pubmed-98416052023-01-17 Stable Monoareno-pentalenes with Two Olefinic Protons Mayer, Péter J. London, Gábor Org Lett [Image: see text] A novel class of stable monoareno-pentalenes is introduced that have an olefinic proton on each five-membered ring of the pentalene subunit. Their synthesis was accomplished via a regioselective carbopalladation cascade reaction between ortho-arylacetyleno gem-dibromoolefins and TIPS-acetylene. These molecules could be experimental probes of magnetic (anti)aromaticity effects. American Chemical Society 2022-12-28 /pmc/articles/PMC9841605/ /pubmed/36576234 http://dx.doi.org/10.1021/acs.orglett.2c03752 Text en © 2022 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by/4.0/Permits the broadest form of re-use including for commercial purposes, provided that author attribution and integrity are maintained (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Mayer, Péter J.
London, Gábor
Stable Monoareno-pentalenes with Two Olefinic Protons
title Stable Monoareno-pentalenes with Two Olefinic Protons
title_full Stable Monoareno-pentalenes with Two Olefinic Protons
title_fullStr Stable Monoareno-pentalenes with Two Olefinic Protons
title_full_unstemmed Stable Monoareno-pentalenes with Two Olefinic Protons
title_short Stable Monoareno-pentalenes with Two Olefinic Protons
title_sort stable monoareno-pentalenes with two olefinic protons
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9841605/
https://www.ncbi.nlm.nih.gov/pubmed/36576234
http://dx.doi.org/10.1021/acs.orglett.2c03752
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