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A novel supramolecular Zn(ii)-metallogel: an efficient microelectronic semiconducting device application

A unique strategy for the synthesis of a supramolecular metallogel employing zinc ions and adipic acid in DMF medium has been established at room temperature. Rheological analysis was used to investigate the mechanical characteristics of the supramolecular Zn(ii)-metallogel. Field emission scanning...

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Detalles Bibliográficos
Autores principales: Karmakar, Kripasindhu, Dey, Arka, Dhibar, Subhendu, Sahu, Rajib, Bhattacharjee, Subham, Karmakar, Priya, Chatterjee, Priyajit, Mondal, Aniruddha, Saha, Bidyut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9844075/
https://www.ncbi.nlm.nih.gov/pubmed/36741164
http://dx.doi.org/10.1039/d2ra07374a
Descripción
Sumario:A unique strategy for the synthesis of a supramolecular metallogel employing zinc ions and adipic acid in DMF medium has been established at room temperature. Rheological analysis was used to investigate the mechanical characteristics of the supramolecular Zn(ii)-metallogel. Field emission scanning electron microscopy and transmission electron microscopy were used to analyse the hexagonal shape morphological features of the Zn(ii)-metallogel. Interestingly, the electrical conductivity is observed in the electronic device with Zn(ii)-metallogel based metal–semiconductor (MS) junctions. All aspects of the metallogel's electrical properties were investigated. The electrical conductivity of the metallogel-based thin film device was 7.38 × 10(−5) S m(−1). The synthesised Zn(ii)-metallogel based device was investigated for its semi-conductive properties, such as its Schottky barrier diode nature.