Halogen-Bonding-Mediated Radical Reactions: The Unexpected Behavior of Piperazine-Based Dithiooxamide Ligands in the Presence of Diiodine

[Image: see text] N,N′-Dialkylpiperazine-2,3-dithiones (R(2)pipdt) were recognized as a class of hexa-atomic cyclic dithiooxamide ligands with peculiar charge-transfer donor properties toward soft electron-acceptors such as noble metal cations and diiodine. The latter interaction is nowadays better...

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Detalles Bibliográficos
Autores principales: Rizzato, Silvia, Manca, Gabriele, Lemée, Marie-Hélène, Marchiò, Luciano, Cesare Marincola, Flaminia, Guerri, Annalisa, Ienco, Andrea, Serpe, Angela, Deplano, Paola
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9846695/
https://www.ncbi.nlm.nih.gov/pubmed/36602377
http://dx.doi.org/10.1021/acs.inorgchem.2c02340

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