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Electronic structure comparisons of isostructural early d- and f-block metal(iii) bis(cyclopentadienyl) silanide complexes
We report the synthesis of the U(iii) bis(cyclopentadienyl) hypersilanide complex [U(Cp′′)(2){Si(SiMe(3))(3)}] (Cp′′ = {C(5)H(3)(SiMe(3))(2)-1,3}), together with isostructural lanthanide and group 4 M(iii) homologues, in order to meaningfully compare metal-silicon bonding between early d- and f-bloc...
| Autores principales: | , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
The Royal Society of Chemistry
2022
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847655/ https://www.ncbi.nlm.nih.gov/pubmed/36741509 http://dx.doi.org/10.1039/d2sc04526e |