Photoactivation of titanium-oxo cluster [Ti(6)O(6)(OR)(6)(O(2)C(t)Bu)(6)]: mechanism, photoactivated structures, and onward reactivity with O(2) to a peroxide complex

The molecular titanium-oxo cluster [Ti(6)O(6)(O(i)Pr)(6)(O(2)C(t)Bu)(6)] (1) can be photoactivated by UV light, resulting in a deeply coloured mixed valent (photoreduced) Ti (iii/iv) cluster, alongside alcohol and ketone (photooxidised) organic products. Mechanistic studies indicate that a two-elect...

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Detalles Bibliográficos
Autores principales: Brown, Stephen E., Mantaloufa, Ioanna, Andrews, Ryan T., Barnes, Thomas J., Lees, Martin R., De Proft, Frank, Cunha, Ana V., Pike, Sebastian D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847671/
https://www.ncbi.nlm.nih.gov/pubmed/36741534
http://dx.doi.org/10.1039/d2sc05671b

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847671/
https://www.ncbi.nlm.nih.gov/pubmed/36741534
http://dx.doi.org/10.1039/d2sc05671b

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