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Regiodivergent metal-catalyzed B(4)- and C(1)-selenylation of o-carboranes

Regiodivergent transition metal-catalyzed B(4)- and C(1)-selenylation reactions of o-carboranes have been demonstrated. Namely, Ru(ii)-catalysis selectively generated B(4)-selenylated o-carboranes from the reaction of o-carborane acids with arylselenyl bromides with the release of carbon dioxide. In...

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Detalles Bibliográficos
Autores principales: Lee, Kyungsup, Harper, Jordan L., Kim, Tae Hyeon, Chan Noh, Hee, Kim, Dongwook, Ha-Yeon Cheong, Paul, Lee, Phil Ho
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9847680/
https://www.ncbi.nlm.nih.gov/pubmed/36741533
http://dx.doi.org/10.1039/d2sc05590b

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