Cargando…
The dodeca-coordinated La©B(8)C(4)(+/0/−) molecular wheels: conflicting aromaticity versus double aromaticity
The transition-metal centered boron molecular wheels have attracted the attention of chemists. The highest deca-coordination number for central metal atoms was observed in D(10h) Ta©B(10)(−) and Nb©B(10)(−) molecular wheels. Here, we report a theoretical study of La©B(8)C(4)(q) (q = +1, 0, −1) clust...
Autores principales: | Wang, Ying-Jin, Zhao, Jia-Xin, Yan, Miao, Feng, Lin-Yan, Miao, Chang-Qing, Liu, Cheng-Qi |
---|---|
Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
|
Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850364/ https://www.ncbi.nlm.nih.gov/pubmed/36756424 http://dx.doi.org/10.1039/d2ra07155j |
Ejemplares similares
-
Aromatic foldamers as scaffolds for metal second coordination sphere design
por: Meunier, Antoine, et al.
Publicado: (2020) -
Searching for double σ- and π-aromaticity in borazine derivatives
por: Pino-Rios, Ricardo, et al.
Publicado: (2020) -
Benzo-thia-fused [n]thienoacenequinodimethanes with small to moderate diradical characters: the role of pro-aromaticity versus anti-aromaticity
por: Shi, Xueliang, et al.
Publicado: (2016) -
Reshaping aromatic frameworks: expansion of aromatic system drives metallabenzenoids to metallapentalenes
por: Li, Qian, et al.
Publicado: (2023) -
Nb(2)©Au(6): a molecular wheel with a short Nb[triple bond, length as m-dash]Nb triple bond coordinated by an Au(6) ring and reinforced by σ aromaticity
por: Jian, Tian, et al.
Publicado: (2017)