Cargando…

High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system

An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the gr...

Descripción completa

Detalles Bibliográficos
Autores principales: Wang, Yi-Jie, Bao, Yu-Fen, Lu, Xiao-Jie, Dong, Jia-Qi, Liu, Ding-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850450/
https://www.ncbi.nlm.nih.gov/pubmed/36756430
http://dx.doi.org/10.1039/d2ra07835j
Descripción
Sumario:An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the greatest catalytic performance in the alkylation reaction with a BHT yield of 85.5%. After four cycles, the yield of BHT exceeded 70%. Overall, the catalyst has excellent catalytic performance and can be utilized as a catalyst for efficient BHT production.