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High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system

An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the gr...

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Autores principales: Wang, Yi-Jie, Bao, Yu-Fen, Lu, Xiao-Jie, Dong, Jia-Qi, Liu, Ding-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: The Royal Society of Chemistry 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850450/
https://www.ncbi.nlm.nih.gov/pubmed/36756430
http://dx.doi.org/10.1039/d2ra07835j
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author Wang, Yi-Jie
Bao, Yu-Fen
Lu, Xiao-Jie
Dong, Jia-Qi
Liu, Ding-Hua
author_facet Wang, Yi-Jie
Bao, Yu-Fen
Lu, Xiao-Jie
Dong, Jia-Qi
Liu, Ding-Hua
author_sort Wang, Yi-Jie
collection PubMed
description An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the greatest catalytic performance in the alkylation reaction with a BHT yield of 85.5%. After four cycles, the yield of BHT exceeded 70%. Overall, the catalyst has excellent catalytic performance and can be utilized as a catalyst for efficient BHT production.
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spelling pubmed-98504502023-02-07 High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system Wang, Yi-Jie Bao, Yu-Fen Lu, Xiao-Jie Dong, Jia-Qi Liu, Ding-Hua RSC Adv Chemistry An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the greatest catalytic performance in the alkylation reaction with a BHT yield of 85.5%. After four cycles, the yield of BHT exceeded 70%. Overall, the catalyst has excellent catalytic performance and can be utilized as a catalyst for efficient BHT production. The Royal Society of Chemistry 2023-01-19 /pmc/articles/PMC9850450/ /pubmed/36756430 http://dx.doi.org/10.1039/d2ra07835j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/
spellingShingle Chemistry
Wang, Yi-Jie
Bao, Yu-Fen
Lu, Xiao-Jie
Dong, Jia-Qi
Liu, Ding-Hua
High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title_full High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title_fullStr High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title_full_unstemmed High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title_short High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
title_sort high-efficiency catalyst cuso(4)/sba-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850450/
https://www.ncbi.nlm.nih.gov/pubmed/36756430
http://dx.doi.org/10.1039/d2ra07835j
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