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High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system
An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the gr...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
The Royal Society of Chemistry
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850450/ https://www.ncbi.nlm.nih.gov/pubmed/36756430 http://dx.doi.org/10.1039/d2ra07835j |
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author | Wang, Yi-Jie Bao, Yu-Fen Lu, Xiao-Jie Dong, Jia-Qi Liu, Ding-Hua |
author_facet | Wang, Yi-Jie Bao, Yu-Fen Lu, Xiao-Jie Dong, Jia-Qi Liu, Ding-Hua |
author_sort | Wang, Yi-Jie |
collection | PubMed |
description | An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the greatest catalytic performance in the alkylation reaction with a BHT yield of 85.5%. After four cycles, the yield of BHT exceeded 70%. Overall, the catalyst has excellent catalytic performance and can be utilized as a catalyst for efficient BHT production. |
format | Online Article Text |
id | pubmed-9850450 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | The Royal Society of Chemistry |
record_format | MEDLINE/PubMed |
spelling | pubmed-98504502023-02-07 High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system Wang, Yi-Jie Bao, Yu-Fen Lu, Xiao-Jie Dong, Jia-Qi Liu, Ding-Hua RSC Adv Chemistry An SBA-15 loaded CuSO(4) catalyst was designed and prepared for the highly selective production of 2,6-di-tert-butyl-p-cresol (BHT) from p-cresol and isobutylene. The acidity of solid acid catalysts was altered by varying the loading amount of CuSO(4). Among them, 10% CuSO(4)/SBA-15 exhibited the greatest catalytic performance in the alkylation reaction with a BHT yield of 85.5%. After four cycles, the yield of BHT exceeded 70%. Overall, the catalyst has excellent catalytic performance and can be utilized as a catalyst for efficient BHT production. The Royal Society of Chemistry 2023-01-19 /pmc/articles/PMC9850450/ /pubmed/36756430 http://dx.doi.org/10.1039/d2ra07835j Text en This journal is © The Royal Society of Chemistry https://creativecommons.org/licenses/by-nc/3.0/ |
spellingShingle | Chemistry Wang, Yi-Jie Bao, Yu-Fen Lu, Xiao-Jie Dong, Jia-Qi Liu, Ding-Hua High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title | High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title_full | High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title_fullStr | High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title_full_unstemmed | High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title_short | High-efficiency catalyst CuSO(4)/SBA-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
title_sort | high-efficiency catalyst cuso(4)/sba-15 toward butylated hydroxytoluene synthesis in a heterogeneous system |
topic | Chemistry |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850450/ https://www.ncbi.nlm.nih.gov/pubmed/36756430 http://dx.doi.org/10.1039/d2ra07835j |
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