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Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications

[Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as ag...

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Autores principales: Singh, Bhupendra Pratap, Sikarwar, Samiksha, Agarwal, Shikha, Singh, Dharmendra Pratap, Pandey, Kamal Kumar, Manohar, Rajiv
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850737/
https://www.ncbi.nlm.nih.gov/pubmed/36687113
http://dx.doi.org/10.1021/acsomega.2c06718
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author Singh, Bhupendra Pratap
Sikarwar, Samiksha
Agarwal, Shikha
Singh, Dharmendra Pratap
Pandey, Kamal Kumar
Manohar, Rajiv
author_facet Singh, Bhupendra Pratap
Sikarwar, Samiksha
Agarwal, Shikha
Singh, Dharmendra Pratap
Pandey, Kamal Kumar
Manohar, Rajiv
author_sort Singh, Bhupendra Pratap
collection PubMed
description [Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as aggregation-induced emission (AIE) electroluminescent composite systems composed of a nematic liquid crystals (NLC) blended with polyethylene-functionalized gold nanospheres (GNSs). The major findings of this study include superior electro-optical properties such as threshold voltage reduction by around 24%. The fall time is reduced by 11.50, 30.33, 49.33, and 63.17% respectively, and rotational viscosity is reduced by 13.86, 32.77, 36.97, and 49.58% for 5.0 × 10(11), 5.0 × 10(12), 2.5 × 10(13), and 5.0 × 10(13) number of GNS-blended liquid crystal (LC) cells. The increased UV absorbance and greatly enhanced luminescence properties have been attributed to surface plasmon resonance near the surface of GNSs and AIE effect risen due to agglomeration of the capping agent with the NLC molecules respectively, and these characteristics make them suitable for new-age display applications.
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spelling pubmed-98507372023-01-20 Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications Singh, Bhupendra Pratap Sikarwar, Samiksha Agarwal, Shikha Singh, Dharmendra Pratap Pandey, Kamal Kumar Manohar, Rajiv ACS Omega [Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as aggregation-induced emission (AIE) electroluminescent composite systems composed of a nematic liquid crystals (NLC) blended with polyethylene-functionalized gold nanospheres (GNSs). The major findings of this study include superior electro-optical properties such as threshold voltage reduction by around 24%. The fall time is reduced by 11.50, 30.33, 49.33, and 63.17% respectively, and rotational viscosity is reduced by 13.86, 32.77, 36.97, and 49.58% for 5.0 × 10(11), 5.0 × 10(12), 2.5 × 10(13), and 5.0 × 10(13) number of GNS-blended liquid crystal (LC) cells. The increased UV absorbance and greatly enhanced luminescence properties have been attributed to surface plasmon resonance near the surface of GNSs and AIE effect risen due to agglomeration of the capping agent with the NLC molecules respectively, and these characteristics make them suitable for new-age display applications. American Chemical Society 2023-01-03 /pmc/articles/PMC9850737/ /pubmed/36687113 http://dx.doi.org/10.1021/acsomega.2c06718 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Singh, Bhupendra Pratap
Sikarwar, Samiksha
Agarwal, Shikha
Singh, Dharmendra Pratap
Pandey, Kamal Kumar
Manohar, Rajiv
Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title_full Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title_fullStr Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title_full_unstemmed Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title_short Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
title_sort chemically functionalized gold nanosphere-blended nematic liquid crystals for photonic applications
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850737/
https://www.ncbi.nlm.nih.gov/pubmed/36687113
http://dx.doi.org/10.1021/acsomega.2c06718
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