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Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications
[Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as ag...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2023
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850737/ https://www.ncbi.nlm.nih.gov/pubmed/36687113 http://dx.doi.org/10.1021/acsomega.2c06718 |
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author | Singh, Bhupendra Pratap Sikarwar, Samiksha Agarwal, Shikha Singh, Dharmendra Pratap Pandey, Kamal Kumar Manohar, Rajiv |
author_facet | Singh, Bhupendra Pratap Sikarwar, Samiksha Agarwal, Shikha Singh, Dharmendra Pratap Pandey, Kamal Kumar Manohar, Rajiv |
author_sort | Singh, Bhupendra Pratap |
collection | PubMed |
description | [Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as aggregation-induced emission (AIE) electroluminescent composite systems composed of a nematic liquid crystals (NLC) blended with polyethylene-functionalized gold nanospheres (GNSs). The major findings of this study include superior electro-optical properties such as threshold voltage reduction by around 24%. The fall time is reduced by 11.50, 30.33, 49.33, and 63.17% respectively, and rotational viscosity is reduced by 13.86, 32.77, 36.97, and 49.58% for 5.0 × 10(11), 5.0 × 10(12), 2.5 × 10(13), and 5.0 × 10(13) number of GNS-blended liquid crystal (LC) cells. The increased UV absorbance and greatly enhanced luminescence properties have been attributed to surface plasmon resonance near the surface of GNSs and AIE effect risen due to agglomeration of the capping agent with the NLC molecules respectively, and these characteristics make them suitable for new-age display applications. |
format | Online Article Text |
id | pubmed-9850737 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | American Chemical Society |
record_format | MEDLINE/PubMed |
spelling | pubmed-98507372023-01-20 Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications Singh, Bhupendra Pratap Sikarwar, Samiksha Agarwal, Shikha Singh, Dharmendra Pratap Pandey, Kamal Kumar Manohar, Rajiv ACS Omega [Image: see text] A demand for functional materials that are capable of tailoring light-emissive properties has apparently been rising nowadays substantially for their utilization in organic optoelectronic devices. Motivated by such promising characteristics, we present highly emissive as well as aggregation-induced emission (AIE) electroluminescent composite systems composed of a nematic liquid crystals (NLC) blended with polyethylene-functionalized gold nanospheres (GNSs). The major findings of this study include superior electro-optical properties such as threshold voltage reduction by around 24%. The fall time is reduced by 11.50, 30.33, 49.33, and 63.17% respectively, and rotational viscosity is reduced by 13.86, 32.77, 36.97, and 49.58% for 5.0 × 10(11), 5.0 × 10(12), 2.5 × 10(13), and 5.0 × 10(13) number of GNS-blended liquid crystal (LC) cells. The increased UV absorbance and greatly enhanced luminescence properties have been attributed to surface plasmon resonance near the surface of GNSs and AIE effect risen due to agglomeration of the capping agent with the NLC molecules respectively, and these characteristics make them suitable for new-age display applications. American Chemical Society 2023-01-03 /pmc/articles/PMC9850737/ /pubmed/36687113 http://dx.doi.org/10.1021/acsomega.2c06718 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/). |
spellingShingle | Singh, Bhupendra Pratap Sikarwar, Samiksha Agarwal, Shikha Singh, Dharmendra Pratap Pandey, Kamal Kumar Manohar, Rajiv Chemically Functionalized Gold Nanosphere-Blended Nematic Liquid Crystals for Photonic Applications |
title | Chemically Functionalized
Gold Nanosphere-Blended
Nematic Liquid Crystals for Photonic Applications |
title_full | Chemically Functionalized
Gold Nanosphere-Blended
Nematic Liquid Crystals for Photonic Applications |
title_fullStr | Chemically Functionalized
Gold Nanosphere-Blended
Nematic Liquid Crystals for Photonic Applications |
title_full_unstemmed | Chemically Functionalized
Gold Nanosphere-Blended
Nematic Liquid Crystals for Photonic Applications |
title_short | Chemically Functionalized
Gold Nanosphere-Blended
Nematic Liquid Crystals for Photonic Applications |
title_sort | chemically functionalized
gold nanosphere-blended
nematic liquid crystals for photonic applications |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9850737/ https://www.ncbi.nlm.nih.gov/pubmed/36687113 http://dx.doi.org/10.1021/acsomega.2c06718 |
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