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A Sterically Tuned Directing Auxiliary Promotes Catalytic 1,2‐Carbofluorination of Alkenyl Carbonyl Compounds

The site‐selective palladium‐catalyzed three‐component coupling of unactivated alkenyl carbonyl compounds, aryl‐ or alkenylboronic acids, and N‐fluorobenzenesulfonimide is described herein. Tuning of the steric environment on the bidentate directing auxiliary enhances regioselectivity and facilitate...

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Detalles Bibliográficos
Autores principales:	Liu, Zhonglin, Oxtoby, Lucas J., Sun, Juntao, Li, Zi‐Qi, Kim, Nana, Davies, Geraint H. M., Engle, Keary M.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2022
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9851970/ https://www.ncbi.nlm.nih.gov/pubmed/36221812 http://dx.doi.org/10.1002/anie.202214153

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