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Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant

As cobalt (Co) has been the most useful element for activating Oxone to generate SO(4)(•−), this study aims to develop a hierarchical catalyst with nanoscale functionality and macroscale convenience by decorating nanoscale Co-based oxides on macroscale supports. Specifically, a facile protocol is pr...

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Autores principales: Mao, Po-Hsin, Kwon, Eilhann, Chang, Hou-Chien, Bui, Ha Manh, Phattarapattamawong, Songkeart, Tsai, Yu-Chih, Lin, Kun-Yi Andrew, Ebrahimi, Afshin, Yee, Yeoh Fei, Yuan, Min-Hao
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9853330/
https://www.ncbi.nlm.nih.gov/pubmed/36558250
http://dx.doi.org/10.3390/nano12244396
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author Mao, Po-Hsin
Kwon, Eilhann
Chang, Hou-Chien
Bui, Ha Manh
Phattarapattamawong, Songkeart
Tsai, Yu-Chih
Lin, Kun-Yi Andrew
Ebrahimi, Afshin
Yee, Yeoh Fei
Yuan, Min-Hao
author_facet Mao, Po-Hsin
Kwon, Eilhann
Chang, Hou-Chien
Bui, Ha Manh
Phattarapattamawong, Songkeart
Tsai, Yu-Chih
Lin, Kun-Yi Andrew
Ebrahimi, Afshin
Yee, Yeoh Fei
Yuan, Min-Hao
author_sort Mao, Po-Hsin
collection PubMed
description As cobalt (Co) has been the most useful element for activating Oxone to generate SO(4)(•−), this study aims to develop a hierarchical catalyst with nanoscale functionality and macroscale convenience by decorating nanoscale Co-based oxides on macroscale supports. Specifically, a facile protocol is proposed by utilizing Cu mesh itself as a Cu source for fabricating CuCo(2)O(4) on Cu mesh. By changing the dosages of the Co precursor and carbamide, various nanostructures of CuCo(2)O(4) grown on a Cu mesh can be afforded, including nanoscale needles, flowers, and sheets. Even though the Cu mesh itself can be also transformed to a Cu-Oxide mesh, the growth of CuCo(2)O(4) on the Cu mesh significantly improves its physical, chemical, and electrochemical properties, making these CuCo(2)O(4)@Cu meshes much more superior catalysts for activating Oxone to degrade the Azo toxicant, Acid Red 27. More interestingly, the flower-like CuCo(2)O(4)@Cu mesh exhibits a higher specific surface area and more superior electrochemical performance, enabling the flower-like CuCo(2)O(4)@Cu mesh to show the highest catalytic activity for Oxone activation to degrade Acid Red 27. The flower-like CuCo(2)O(4)@Cu mesh also exhibits a much lower E(a) of Acid Red 27 degradation than the reported catalysts. These results demonstrate that CuCo(2)O(4)@Cu meshes are advantageous heterogeneous catalysts for Oxone activation, and especially, the flower-like CuCo(2)O(4)@Cu mesh appears as the most effective CuCo(2)O(4)@Cu mesh to eliminate the toxic Acid Red 27.
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spelling pubmed-98533302023-01-21 Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant Mao, Po-Hsin Kwon, Eilhann Chang, Hou-Chien Bui, Ha Manh Phattarapattamawong, Songkeart Tsai, Yu-Chih Lin, Kun-Yi Andrew Ebrahimi, Afshin Yee, Yeoh Fei Yuan, Min-Hao Nanomaterials (Basel) Article As cobalt (Co) has been the most useful element for activating Oxone to generate SO(4)(•−), this study aims to develop a hierarchical catalyst with nanoscale functionality and macroscale convenience by decorating nanoscale Co-based oxides on macroscale supports. Specifically, a facile protocol is proposed by utilizing Cu mesh itself as a Cu source for fabricating CuCo(2)O(4) on Cu mesh. By changing the dosages of the Co precursor and carbamide, various nanostructures of CuCo(2)O(4) grown on a Cu mesh can be afforded, including nanoscale needles, flowers, and sheets. Even though the Cu mesh itself can be also transformed to a Cu-Oxide mesh, the growth of CuCo(2)O(4) on the Cu mesh significantly improves its physical, chemical, and electrochemical properties, making these CuCo(2)O(4)@Cu meshes much more superior catalysts for activating Oxone to degrade the Azo toxicant, Acid Red 27. More interestingly, the flower-like CuCo(2)O(4)@Cu mesh exhibits a higher specific surface area and more superior electrochemical performance, enabling the flower-like CuCo(2)O(4)@Cu mesh to show the highest catalytic activity for Oxone activation to degrade Acid Red 27. The flower-like CuCo(2)O(4)@Cu mesh also exhibits a much lower E(a) of Acid Red 27 degradation than the reported catalysts. These results demonstrate that CuCo(2)O(4)@Cu meshes are advantageous heterogeneous catalysts for Oxone activation, and especially, the flower-like CuCo(2)O(4)@Cu mesh appears as the most effective CuCo(2)O(4)@Cu mesh to eliminate the toxic Acid Red 27. MDPI 2022-12-09 /pmc/articles/PMC9853330/ /pubmed/36558250 http://dx.doi.org/10.3390/nano12244396 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mao, Po-Hsin
Kwon, Eilhann
Chang, Hou-Chien
Bui, Ha Manh
Phattarapattamawong, Songkeart
Tsai, Yu-Chih
Lin, Kun-Yi Andrew
Ebrahimi, Afshin
Yee, Yeoh Fei
Yuan, Min-Hao
Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title_full Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title_fullStr Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title_full_unstemmed Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title_short Modulating Direct Growth of Copper Cobaltite Nanostructure on Copper Mesh as a Hierarchical Catalyst of Oxone Activation for Efficient Elimination of Azo Toxicant
title_sort modulating direct growth of copper cobaltite nanostructure on copper mesh as a hierarchical catalyst of oxone activation for efficient elimination of azo toxicant
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9853330/
https://www.ncbi.nlm.nih.gov/pubmed/36558250
http://dx.doi.org/10.3390/nano12244396
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