Photoinduced Halogen-Atom Transfer by N-Heterocyclic Carbene-Ligated Boryl Radicals for C(sp(3))–C(sp(3)) Bond Formation

[Image: see text] Herein, we present a comprehensive study on the use of N-heterocyclic carbene (NHC)-ligated boryl radicals to enable C(sp(3))–C(sp(3)) bond formation under visible-light irradiation via Halogen-Atom Transfer (XAT). The methodology relies on the use of an acridinium dye to generate...

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Detalles Bibliográficos
Autores principales: Wan, Ting, Capaldo, Luca, Ravelli, Davide, Vitullo, Walter, de Zwart, Felix J., de Bruin, Bas, Noël, Timothy
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2022
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9853867/
https://www.ncbi.nlm.nih.gov/pubmed/36583709
http://dx.doi.org/10.1021/jacs.2c10444

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