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Double-Network Hydrogel Films Based on Cellulose Derivatives and κ-Carrageenan with Enhanced Mechanical Strength and Superabsorbent Properties
Covalently crosslinked sodium carboxymethyl cellulose (CMC)–hydroxyethyl cellulose (HEC) hydrogel films were prepared using citric acid (CA) as the crosslinking agent. Thereafter, the physically crosslinked κ-carrageenan (κ-CG) polymer was introduced into the CMC–HEC hydrogel structure, yielding κ-C...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2022
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9858413/ https://www.ncbi.nlm.nih.gov/pubmed/36661788 http://dx.doi.org/10.3390/gels9010020 |
Sumario: | Covalently crosslinked sodium carboxymethyl cellulose (CMC)–hydroxyethyl cellulose (HEC) hydrogel films were prepared using citric acid (CA) as the crosslinking agent. Thereafter, the physically crosslinked κ-carrageenan (κ-CG) polymer was introduced into the CMC–HEC hydrogel structure, yielding κ-CG/CMC–HEC double network (DN) hydrogels. The κ-CG physical network provided sacrificial bonding, which effectively dissipated the stretching energy, resulting in an increase in the tensile modulus, tensile strength, and fracture energy of the DN hydrogels by 459%, 305%, and 398%, respectively, compared with those of the CMC–HEC single network (SN) hydrogel. The dried hydrogels exhibited excellent water absorbency with a maximum water-absorption capacity of 66 g/g in distilled water. Compared with the dried covalent SN gel, the dried DN hydrogels exhibited enhanced absorbency under load, attributed to their improved mechanical properties. The water-absorption capacities and kinetics were dependent on the size of the dried gel and the pH of the water. |
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