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Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination

Functional aerogels composed of regenerated cellulose and tungsten oxide were fabricated by implanting tungsten-oxide nanodots into regenerated cellulose fiber. This superfast photochromic property benefitted from the small size and even distribution of tungsten oxide, which was caused by the confin...

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Autores principales: Tang, Yanjin, Lai, Yuhan, Gao, Ruiqin, Chen, Yuxuan, Xiong, Kexin, Ye, Juan, Zheng, Qi, Fang, Zhenxing, Pang, Guangsheng, Lee, Hoo-Jeong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2022
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9858587/
https://www.ncbi.nlm.nih.gov/pubmed/36661778
http://dx.doi.org/10.3390/gels9010010
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author Tang, Yanjin
Lai, Yuhan
Gao, Ruiqin
Chen, Yuxuan
Xiong, Kexin
Ye, Juan
Zheng, Qi
Fang, Zhenxing
Pang, Guangsheng
Lee, Hoo-Jeong
author_facet Tang, Yanjin
Lai, Yuhan
Gao, Ruiqin
Chen, Yuxuan
Xiong, Kexin
Ye, Juan
Zheng, Qi
Fang, Zhenxing
Pang, Guangsheng
Lee, Hoo-Jeong
author_sort Tang, Yanjin
collection PubMed
description Functional aerogels composed of regenerated cellulose and tungsten oxide were fabricated by implanting tungsten-oxide nanodots into regenerated cellulose fiber. This superfast photochromic property benefitted from the small size and even distribution of tungsten oxide, which was caused by the confinement effect of the regenerated cellulose fiber. The composite was characterized using XRD and TEM to illustrate the successful loading of tungsten oxide. The composite turned from pale white to bright blue under ambient solar irradiation in five seconds. The evidence of solar absorption and electron paramagnetic resonance (EPR) demonstrated the fast photochromic nature of the composite and its mechanism. Furthermore, carbon fiber filled with preferential growth tungsten-oxide nanorods was obtained by annealing the photochromic composite in a N(2) atmosphere. This annealed product exhibited good absorption across the whole solar spectrum and revealed an excellent photothermal conversion performance. The water evaporation rate reached 1.75 kg m(−2) h(−1) under one sun illumination, which is 4.4 times higher than that of pure water. The photothermal conversion efficiency was 85%, which shows its potential application prospects in seawater desalination.
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spelling pubmed-98585872023-01-21 Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination Tang, Yanjin Lai, Yuhan Gao, Ruiqin Chen, Yuxuan Xiong, Kexin Ye, Juan Zheng, Qi Fang, Zhenxing Pang, Guangsheng Lee, Hoo-Jeong Gels Article Functional aerogels composed of regenerated cellulose and tungsten oxide were fabricated by implanting tungsten-oxide nanodots into regenerated cellulose fiber. This superfast photochromic property benefitted from the small size and even distribution of tungsten oxide, which was caused by the confinement effect of the regenerated cellulose fiber. The composite was characterized using XRD and TEM to illustrate the successful loading of tungsten oxide. The composite turned from pale white to bright blue under ambient solar irradiation in five seconds. The evidence of solar absorption and electron paramagnetic resonance (EPR) demonstrated the fast photochromic nature of the composite and its mechanism. Furthermore, carbon fiber filled with preferential growth tungsten-oxide nanorods was obtained by annealing the photochromic composite in a N(2) atmosphere. This annealed product exhibited good absorption across the whole solar spectrum and revealed an excellent photothermal conversion performance. The water evaporation rate reached 1.75 kg m(−2) h(−1) under one sun illumination, which is 4.4 times higher than that of pure water. The photothermal conversion efficiency was 85%, which shows its potential application prospects in seawater desalination. MDPI 2022-12-25 /pmc/articles/PMC9858587/ /pubmed/36661778 http://dx.doi.org/10.3390/gels9010010 Text en © 2022 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Tang, Yanjin
Lai, Yuhan
Gao, Ruiqin
Chen, Yuxuan
Xiong, Kexin
Ye, Juan
Zheng, Qi
Fang, Zhenxing
Pang, Guangsheng
Lee, Hoo-Jeong
Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title_full Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title_fullStr Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title_full_unstemmed Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title_short Functional Aerogels Composed of Regenerated Cellulose and Tungsten Oxide for UV Detection and Seawater Desalination
title_sort functional aerogels composed of regenerated cellulose and tungsten oxide for uv detection and seawater desalination
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9858587/
https://www.ncbi.nlm.nih.gov/pubmed/36661778
http://dx.doi.org/10.3390/gels9010010
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