Wettability Studies of Capillary PTFE Membranes Applied for Membrane Distillation

In the present study, the membrane distillation (MD) process was studied with the use of commercial polytetrafluoroethylene (PTFE) capillary membranes. For this purpose, both solutions with NaCl concentrations up to 300 g/L and brines contaminated with oil (70–120 mg/L) were used as feeds. The membrane’s wetting resistance was tested by conducting long-term experiments for over 3500 h. Using detailed studies, it has been shown that increasing the salt concentration from 35 to 300 g/L resulted in a 50% reduction in the permeate flux. Nevertheless, the membranes retained 100% of the salt rejection after 2000 h of the module’s operation. Moreover, it has been found that performing the MD process with brines contaminated with oil (120 mg/L) led to the wetting of some membranes pores, which it turn resulted in an increase in the distillate’s conductivity to 450 µS/cm after 700 h running the process. The mechanism of pore wetting by oil droplets adsorbed on the membrane’s surface was presented. Finally, the proposed method of membrane cleaning with the use of a solvent allowed restoring the initial MD module’s performance. Consequently, both the permeate flux and distillate conductivity were stable during the MD of the feed containing 35 g/L of NaCl over the next 280 h.