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Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)

Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing...

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Detalles Bibliográficos
Autores principales: Rakhshani, Somayyeh, Araneo, Rodolfo, Pucci, Andrea, Rinaldi, Antonio, Giuliani, Chiara, Pozio, Alfonso
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860756/
https://www.ncbi.nlm.nih.gov/pubmed/36676916
http://dx.doi.org/10.3390/membranes13010109
Descripción
Sumario:Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard(®) 3401) with a commercially available functional group (Fumion(®) FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO(2) absorption on membrane conductivity.