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Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)

Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing...

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Autores principales: Rakhshani, Somayyeh, Araneo, Rodolfo, Pucci, Andrea, Rinaldi, Antonio, Giuliani, Chiara, Pozio, Alfonso
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860756/
https://www.ncbi.nlm.nih.gov/pubmed/36676916
http://dx.doi.org/10.3390/membranes13010109
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author Rakhshani, Somayyeh
Araneo, Rodolfo
Pucci, Andrea
Rinaldi, Antonio
Giuliani, Chiara
Pozio, Alfonso
author_facet Rakhshani, Somayyeh
Araneo, Rodolfo
Pucci, Andrea
Rinaldi, Antonio
Giuliani, Chiara
Pozio, Alfonso
author_sort Rakhshani, Somayyeh
collection PubMed
description Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard(®) 3401) with a commercially available functional group (Fumion(®) FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO(2) absorption on membrane conductivity.
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spelling pubmed-98607562023-01-22 Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE) Rakhshani, Somayyeh Araneo, Rodolfo Pucci, Andrea Rinaldi, Antonio Giuliani, Chiara Pozio, Alfonso Membranes (Basel) Article Anion exchange membranes (AEM) have gained attention recently as a promising candidate for low-cost water electrolysis systems to produce hydrogen, linked with renewable energy resources as a sustainable alternative to fossil fuels. The development of potential materials for producing and analyzing AEM is an imperative step towards commercialization and plays a competitive role in the hydrogen production industry. In this article, we developed a composite anion exchange membrane prepared by activating a commercial support structure (Celgard(®) 3401) with a commercially available functional group (Fumion(®) FAA-3) through a phase-inversion process. Fourier-transform infrared spectroscopy (FTIR) and Scanning Electron Microscopy (SEM) analysis demonstrated the phase-inversion procedure as an effective methodology. Furthermore, the cell performance test result (with Celgard/Fumion) was very promising and even better in comparison with a commercial membrane commonly applied in alkaline electrolysis (Fumasep). We also developed a testing procedure for membrane performance evaluation during electrolysis which is very critical considering the effect of CO(2) absorption on membrane conductivity. MDPI 2023-01-14 /pmc/articles/PMC9860756/ /pubmed/36676916 http://dx.doi.org/10.3390/membranes13010109 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Rakhshani, Somayyeh
Araneo, Rodolfo
Pucci, Andrea
Rinaldi, Antonio
Giuliani, Chiara
Pozio, Alfonso
Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title_full Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title_fullStr Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title_full_unstemmed Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title_short Synthesis and Characterization of a Composite Anion Exchange Membrane for Water Electrolyzers (AEMWE)
title_sort synthesis and characterization of a composite anion exchange membrane for water electrolyzers (aemwe)
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9860756/
https://www.ncbi.nlm.nih.gov/pubmed/36676916
http://dx.doi.org/10.3390/membranes13010109
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