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Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions
Formic acid has recently been revealed to be an excellent hydrogen carrier, and interest in the development of efficient and selective catalysts towards its dehydrogenation has grown. This reaction has been widely explored using homogeneous catalysts; however, from a practical and scalable point of...
Autores principales: | , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9861380/ https://www.ncbi.nlm.nih.gov/pubmed/36676208 http://dx.doi.org/10.3390/ma16020472 |
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author | Ruiz-López, Estela Ribota Peláez, María Blasco Ruz, María Domínguez Leal, María Isabel Martínez Tejada, Marcela Ivanova, Svetlana Centeno, Miguel Ángel |
author_facet | Ruiz-López, Estela Ribota Peláez, María Blasco Ruz, María Domínguez Leal, María Isabel Martínez Tejada, Marcela Ivanova, Svetlana Centeno, Miguel Ángel |
author_sort | Ruiz-López, Estela |
collection | PubMed |
description | Formic acid has recently been revealed to be an excellent hydrogen carrier, and interest in the development of efficient and selective catalysts towards its dehydrogenation has grown. This reaction has been widely explored using homogeneous catalysts; however, from a practical and scalable point of view, heterogeneous catalysts are usually preferred in industry. In this work, formic acid dehydrogenation reactions in both liquid- and vapor-phase conditions have been investigated using heterogeneous catalysts based on mono- or bimetallic Pd/Ru. In all of the explored conditions, the catalysts showed good catalytic activity and selectivity towards the dehydrogenation reaction, avoiding the formation of undesired CO. |
format | Online Article Text |
id | pubmed-9861380 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-98613802023-01-22 Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions Ruiz-López, Estela Ribota Peláez, María Blasco Ruz, María Domínguez Leal, María Isabel Martínez Tejada, Marcela Ivanova, Svetlana Centeno, Miguel Ángel Materials (Basel) Article Formic acid has recently been revealed to be an excellent hydrogen carrier, and interest in the development of efficient and selective catalysts towards its dehydrogenation has grown. This reaction has been widely explored using homogeneous catalysts; however, from a practical and scalable point of view, heterogeneous catalysts are usually preferred in industry. In this work, formic acid dehydrogenation reactions in both liquid- and vapor-phase conditions have been investigated using heterogeneous catalysts based on mono- or bimetallic Pd/Ru. In all of the explored conditions, the catalysts showed good catalytic activity and selectivity towards the dehydrogenation reaction, avoiding the formation of undesired CO. MDPI 2023-01-04 /pmc/articles/PMC9861380/ /pubmed/36676208 http://dx.doi.org/10.3390/ma16020472 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Ruiz-López, Estela Ribota Peláez, María Blasco Ruz, María Domínguez Leal, María Isabel Martínez Tejada, Marcela Ivanova, Svetlana Centeno, Miguel Ángel Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title | Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title_full | Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title_fullStr | Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title_full_unstemmed | Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title_short | Formic Acid Dehydrogenation over Ru- and Pd-Based Catalysts: Gas- vs. Liquid-Phase Reactions |
title_sort | formic acid dehydrogenation over ru- and pd-based catalysts: gas- vs. liquid-phase reactions |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9861380/ https://www.ncbi.nlm.nih.gov/pubmed/36676208 http://dx.doi.org/10.3390/ma16020472 |
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