Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry

The review presents extensive data (from the author’s work and the literature) on the stereochemical structure of functionalized organophosphorus azoles (pyrroles, pyrazoles, imidazoles and benzazoles) and related compounds, using multinuclear (1)H, (13)C, (31)P NMR spectroscopy and quantum chemistr...

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Detalles Bibliográficos
Autor principal: Larina, Lyudmila
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Review
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9862086/
https://www.ncbi.nlm.nih.gov/pubmed/36677725
http://dx.doi.org/10.3390/molecules28020669
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author Larina, Lyudmila
author_facet Larina, Lyudmila
author_sort Larina, Lyudmila
collection PubMed
description The review presents extensive data (from the author’s work and the literature) on the stereochemical structure of functionalized organophosphorus azoles (pyrroles, pyrazoles, imidazoles and benzazoles) and related compounds, using multinuclear (1)H, (13)C, (31)P NMR spectroscopy and quantum chemistry. (31)P NMR spectroscopy, combined with high-level quantum-chemical calculations, is the most convenient and reliable approach to studying tetra-, penta-, and hexacoordinated phosphorus atoms of phosphorylated N-vinylazoles and evaluating their Z/E isomerization.
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spelling pubmed-98620862023-01-22 Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry Larina, Lyudmila Molecules Review The review presents extensive data (from the author’s work and the literature) on the stereochemical structure of functionalized organophosphorus azoles (pyrroles, pyrazoles, imidazoles and benzazoles) and related compounds, using multinuclear (1)H, (13)C, (31)P NMR spectroscopy and quantum chemistry. (31)P NMR spectroscopy, combined with high-level quantum-chemical calculations, is the most convenient and reliable approach to studying tetra-, penta-, and hexacoordinated phosphorus atoms of phosphorylated N-vinylazoles and evaluating their Z/E isomerization. MDPI 2023-01-09 /pmc/articles/PMC9862086/ /pubmed/36677725 http://dx.doi.org/10.3390/molecules28020669 Text en © 2023 by the author. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Review
Larina, Lyudmila
Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title_full Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title_fullStr Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title_full_unstemmed Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title_short Organophosphorus Azoles Incorporating a Tetra-, Penta-, and Hexacoordinated Phosphorus Atom: NMR Spectroscopy and Quantum Chemistry
title_sort organophosphorus azoles incorporating a tetra-, penta-, and hexacoordinated phosphorus atom: nmr spectroscopy and quantum chemistry
topic Review
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9862086/
https://www.ncbi.nlm.nih.gov/pubmed/36677725
http://dx.doi.org/10.3390/molecules28020669
work_keys_str_mv AT larinalyudmila organophosphorusazolesincorporatingatetrapentaandhexacoordinatedphosphorusatomnmrspectroscopyandquantumchemistry

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