Formation of Thick Immersion Coatings and Residual Stress Evaluation in the System ZrB(2)–ZrO(2): Experimental and Numerical Investigation

The combination of various oxide ceramics in layered and functionally graded composites allows for the development of novel materials, including for high-temperature applications. This study demonstrates the possibility of obtaining a thick ZrO(2)-based coating on a ZrB(2)–SiC ceramic substrate by the immersion method. For better wettability, the porous ZrB(2)–SiC substrate is treated with cold plasma without changing the structure and phase composition of the surface. Immersion of the substrate in a ZrO(2)-based slurry results in the formation of a gradient transition layer due to ZrO(2) particle penetration into the pore volume. The interfacial residual microstresses are evaluated experimentally. The residual macrostresses in the samples are calculated by finite element simulation. It is shown that the thermal residual stresses in the ZrB(2)–SiC substrate are compressive and do not exceed 43 MPa. In the ZrO(2) coating and transition layers of the composite, the residual stresses are tensile. Their values increase as they get closer to the outer layer of the ZrO(2) coating and reach 1525 MPa. This confirms the conclusions about the presence of tensile residual stresses made in the experimental part of the work when observing crack propagation in the surface layers during indentation.