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The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries

The objective of this work was to study the electrochemical behavior of AB(5) alloy and its composite with Pd nanoparticles in selected ionic liquids. The protic ionic liquid (diethylmethylammonium triflate) and the mixture of aprotic ionic liquid (1-ethyl-3-methylimidazolium methanesulfonate) with...

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Autores principales: Hubkowska, Katarzyna, Pająk, Małgorzata, Soszko, Michał, Czerwiński, Andrzej
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865131/
https://www.ncbi.nlm.nih.gov/pubmed/36677914
http://dx.doi.org/10.3390/molecules28020856
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author Hubkowska, Katarzyna
Pająk, Małgorzata
Soszko, Michał
Czerwiński, Andrzej
author_facet Hubkowska, Katarzyna
Pająk, Małgorzata
Soszko, Michał
Czerwiński, Andrzej
author_sort Hubkowska, Katarzyna
collection PubMed
description The objective of this work was to study the electrochemical behavior of AB(5) alloy and its composite with Pd nanoparticles in selected ionic liquids. The protic ionic liquid (diethylmethylammonium triflate) and the mixture of aprotic ionic liquid (1-ethyl-3-methylimidazolium methanesulfonate) with parent superacid were used as electrolytes in the process of hydrogen electrosorption in AB(5) alloy electrodes. The impact of the surface modification of AB(5) electrode with Pd nanoparticles has been checked. The studies revealed that the highest hydrogen absorption capacity can be obtained in Pd-NPs-AB(5) electrode in DEMA-TFO. It was found that the surface modification with Pd-NPs facilitates the activation of the electrode and results in stabilization of the plateau potential of discharging. The studies show that more effort should be put into the synthesis of less corrosive tailored ionic liquids suitable to be used as electrolytes in hydride batteries.
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spelling pubmed-98651312023-01-22 The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries Hubkowska, Katarzyna Pająk, Małgorzata Soszko, Michał Czerwiński, Andrzej Molecules Communication The objective of this work was to study the electrochemical behavior of AB(5) alloy and its composite with Pd nanoparticles in selected ionic liquids. The protic ionic liquid (diethylmethylammonium triflate) and the mixture of aprotic ionic liquid (1-ethyl-3-methylimidazolium methanesulfonate) with parent superacid were used as electrolytes in the process of hydrogen electrosorption in AB(5) alloy electrodes. The impact of the surface modification of AB(5) electrode with Pd nanoparticles has been checked. The studies revealed that the highest hydrogen absorption capacity can be obtained in Pd-NPs-AB(5) electrode in DEMA-TFO. It was found that the surface modification with Pd-NPs facilitates the activation of the electrode and results in stabilization of the plateau potential of discharging. The studies show that more effort should be put into the synthesis of less corrosive tailored ionic liquids suitable to be used as electrolytes in hydride batteries. MDPI 2023-01-14 /pmc/articles/PMC9865131/ /pubmed/36677914 http://dx.doi.org/10.3390/molecules28020856 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Communication
Hubkowska, Katarzyna
Pająk, Małgorzata
Soszko, Michał
Czerwiński, Andrzej
The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title_full The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title_fullStr The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title_full_unstemmed The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title_short The Electrochemical Behavior of Unmodified and Pd-NPs Modified AB(5) Hydrogen Storage Alloy in Selected Protic and Aprotic Ionic Liquids (ILs): Towards ILs-Based Electrolytes for Ni-MH Batteries
title_sort electrochemical behavior of unmodified and pd-nps modified ab(5) hydrogen storage alloy in selected protic and aprotic ionic liquids (ils): towards ils-based electrolytes for ni-mh batteries
topic Communication
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865131/
https://www.ncbi.nlm.nih.gov/pubmed/36677914
http://dx.doi.org/10.3390/molecules28020856
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