A Novel Adsorbent of Attapulgite & Carbon Composites Derived from Spent Bleaching Earth for Synergistic Removal of Copper and Tetracycline in Water

Simultaneously eliminating tetracycline (TC) and copper (Cu-II) from wastewater was investigated by applying a novel adsorbent fabricated by transforming spent bleaching earth (SBE) into attapulgite & carbon composites (A&Cs). Pyrolysis temperature for A&Cs preparation exhibited a positive effect on Cu(II) adsorption, while the AC500 possessed the greatest performance for TC remediation. Interestingly, a synergistic effect instead of competitive adsorption occurred between Cu(II) and TC under the combined binary system, as both TC and Cu(II) adsorption amount on A&C500 increased more than that in the single system, which could be mainly attributed to the bridge actions between the TC and Cu(II). In addition, hydrogen bonding, ᴨ-ᴨ EDA interaction, pore-filling and complexation exerted significant roles in the adsorption process of TC and Cu(II). In general, this study offered a new perspective on the regeneration of livestock and poultry industry wastewater polluted with antibiotics and heavy metals.