X-H Bond Insertion Promoted by Heterogeneous Dirhodium Metal–Organic Cage with Alkynes as Safe Carbene Precursors

A facile and efficient methodology for the generation of the C-X (X = Si, B) bond through a carbene insertion process was demonstrated using a dirhodium metal–organic cage, MOC-Rh-1, as a heterogeneous catalyst. A series of functionalized alkynes were utilized as safe carbene precursors to furnish S...

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Detalles Bibliográficos
Autores principales: Chen, Lianfen, Zhao, Chaoyi, Mo, Weixian, Li, Chunsheng, Lin, Xiaoming
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865382/
https://www.ncbi.nlm.nih.gov/pubmed/36677665
http://dx.doi.org/10.3390/molecules28020608

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865382/
https://www.ncbi.nlm.nih.gov/pubmed/36677665
http://dx.doi.org/10.3390/molecules28020608

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