Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization

Heterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of h...

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Autores principales: Mahmoud, Nadine, Awassa, Jazia, Toufaily, Joumana, Lebeau, Bénédicte, Daou, T. Jean, Cormier, Morgan, Goddard, Jean-Philippe
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2023
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865568/
https://www.ncbi.nlm.nih.gov/pubmed/36677607
http://dx.doi.org/10.3390/molecules28020549
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author Mahmoud, Nadine
Awassa, Jazia
Toufaily, Joumana
Lebeau, Bénédicte
Daou, T. Jean
Cormier, Morgan
Goddard, Jean-Philippe
author_facet Mahmoud, Nadine
Awassa, Jazia
Toufaily, Joumana
Lebeau, Bénédicte
Daou, T. Jean
Cormier, Morgan
Goddard, Jean-Philippe
author_sort Mahmoud, Nadine
collection PubMed
description Heterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of hybrid inorganic/organic photocatalysts based on silica mesoporous material and Eosin Y. These results highlight the influence of non-covalent interactions between the material support and the reagent impacting the selectivity of the reaction.
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spelling pubmed-98655682023-01-22 Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization Mahmoud, Nadine Awassa, Jazia Toufaily, Joumana Lebeau, Bénédicte Daou, T. Jean Cormier, Morgan Goddard, Jean-Philippe Molecules Article Heterogenization of the photocatalyst appears to be a valuable solution to reach sustainable processes. Rapid and efficient synthesis of supported photocatalyst is still a remaining challenge and the choice of the support material is crucial. The present study aims at preparing a new generation of hybrid inorganic/organic photocatalysts based on silica mesoporous material and Eosin Y. These results highlight the influence of non-covalent interactions between the material support and the reagent impacting the selectivity of the reaction. MDPI 2023-01-05 /pmc/articles/PMC9865568/ /pubmed/36677607 http://dx.doi.org/10.3390/molecules28020549 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/).
spellingShingle Article
Mahmoud, Nadine
Awassa, Jazia
Toufaily, Joumana
Lebeau, Bénédicte
Daou, T. Jean
Cormier, Morgan
Goddard, Jean-Philippe
Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title_full Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title_fullStr Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title_full_unstemmed Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title_short Heterogeneous Photoredox Catalysis Based on Silica Mesoporous Material and Eosin Y: Impact of Material Support on Selectivity of Radical Cyclization
title_sort heterogeneous photoredox catalysis based on silica mesoporous material and eosin y: impact of material support on selectivity of radical cyclization
topic Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9865568/
https://www.ncbi.nlm.nih.gov/pubmed/36677607
http://dx.doi.org/10.3390/molecules28020549
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