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Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies
This paper estimates the suitability of the strongly basic anion exchangers, Dowex PSR2 and Dowex PSR3, as sorbents of nickel ions in aqueous solutions. These actions are aimed at searching for new solutions due to the growing discharge of nickel into wastewaters, primarily due to its addition to st...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
MDPI
2023
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9866840/ https://www.ncbi.nlm.nih.gov/pubmed/36676380 http://dx.doi.org/10.3390/ma16020644 |
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author | Bąk, Justyna Sofińska-Chmiel, Weronika Gajewska, Maria Malinowska, Paulina Kołodyńska, Dorota |
author_facet | Bąk, Justyna Sofińska-Chmiel, Weronika Gajewska, Maria Malinowska, Paulina Kołodyńska, Dorota |
author_sort | Bąk, Justyna |
collection | PubMed |
description | This paper estimates the suitability of the strongly basic anion exchangers, Dowex PSR2 and Dowex PSR3, as sorbents of nickel ions in aqueous solutions. These actions are aimed at searching for new solutions due to the growing discharge of nickel into wastewaters, primarily due to its addition to steel. The nickel sorption experiments were conducted under static conditions and resulted in the optimization of pH, phase contact time, initial solution concentration, and temperature. The next step was to calculate the kinetic, isothermal, and thermodynamic parameters. Moreover, the ion exchangers were characterized by means of Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and CHN elemental analysis. It was found that the sorption process was most effective at pH 6 after 240 min and at the temperature of 293 K. The values of the thermodynamic parameters revealed that the adsorption was exothermic and spontaneous. The physicochemical analyses combined with the experimental research enabled determination of the sorption mechanism of Ni(II) ions. |
format | Online Article Text |
id | pubmed-9866840 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2023 |
publisher | MDPI |
record_format | MEDLINE/PubMed |
spelling | pubmed-98668402023-01-22 Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies Bąk, Justyna Sofińska-Chmiel, Weronika Gajewska, Maria Malinowska, Paulina Kołodyńska, Dorota Materials (Basel) Article This paper estimates the suitability of the strongly basic anion exchangers, Dowex PSR2 and Dowex PSR3, as sorbents of nickel ions in aqueous solutions. These actions are aimed at searching for new solutions due to the growing discharge of nickel into wastewaters, primarily due to its addition to steel. The nickel sorption experiments were conducted under static conditions and resulted in the optimization of pH, phase contact time, initial solution concentration, and temperature. The next step was to calculate the kinetic, isothermal, and thermodynamic parameters. Moreover, the ion exchangers were characterized by means of Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and CHN elemental analysis. It was found that the sorption process was most effective at pH 6 after 240 min and at the temperature of 293 K. The values of the thermodynamic parameters revealed that the adsorption was exothermic and spontaneous. The physicochemical analyses combined with the experimental research enabled determination of the sorption mechanism of Ni(II) ions. MDPI 2023-01-09 /pmc/articles/PMC9866840/ /pubmed/36676380 http://dx.doi.org/10.3390/ma16020644 Text en © 2023 by the authors. https://creativecommons.org/licenses/by/4.0/Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). |
spellingShingle | Article Bąk, Justyna Sofińska-Chmiel, Weronika Gajewska, Maria Malinowska, Paulina Kołodyńska, Dorota Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title | Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title_full | Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title_fullStr | Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title_full_unstemmed | Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title_short | Determination of the Ni(II) Ions Sorption Mechanism on Dowex PSR2 and Dowex PSR3 Ion Exchangers Based on Spectroscopic Studies |
title_sort | determination of the ni(ii) ions sorption mechanism on dowex psr2 and dowex psr3 ion exchangers based on spectroscopic studies |
topic | Article |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9866840/ https://www.ncbi.nlm.nih.gov/pubmed/36676380 http://dx.doi.org/10.3390/ma16020644 |
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