Cargando…

Reversible and Irreversible Cation Intercalation in NiFeO(x) Oxygen Evolution Catalysts in Alkaline Media

[Image: see text] For electrocatalysts with a layered structure, ion intercalation is a common phenomenon. Gaining reliable information about the intercalation of ions from the electrolyte is indispensable for a better understanding of the catalytic performance of these electrocatalysts. Here, we ta...

Descripción completa

Detalles Bibliográficos
Autores principales: Trzesniowski, Hanna, Deka, Nipon, van der Heijden, Onno, Golnak, Ronny, Xiao, Jie, Koper, Marc T. M., Seidel, Robert, Mom, Rik V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9870210/
https://www.ncbi.nlm.nih.gov/pubmed/36629512
http://dx.doi.org/10.1021/acs.jpclett.2c03336
Descripción
Sumario:[Image: see text] For electrocatalysts with a layered structure, ion intercalation is a common phenomenon. Gaining reliable information about the intercalation of ions from the electrolyte is indispensable for a better understanding of the catalytic performance of these electrocatalysts. Here, we take a holistic approach for following intercalation processes by studying the dynamics of the catalyst, water molecules, and ions during intercalation using operando soft X-ray absorption spectroscopy (XAS). Sodium and oxygen K-edge and nickel L-edge spectra were used to investigate the Na(+) intercalation in a Ni(0.8)Fe(0.2)O(x) electrocatalyst during the oxygen evolution reaction (OER) in NaOH (0.1 M). The Na K-edge spectra show an irreversible intensity increase upon initial potential cycling and a reversible intensity increase at the intercalation potential, 1.45 V(RHE), coinciding with an increase in the Ni oxidation state. Simultaneously, the O K-edge spectra show that the Na(+) intercalation does not significantly impact the hydration of the catalyst.