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Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics

The effects of sintering conditions on the microstructure, giant dielectric response, and electrical properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) (NYCTTaO) were studied. A single phase of Na(1/2)Y(1/2)Cu(3)Ti(4)O(12) and a high density (>98.5%) were obtained in the sintered NYCTTaO cer...

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Autores principales: Saengvong, Pariwat, Boonlakhorn, Jakkree, Jumpatam, Jutapol, Chanlek, Narong, Prasongkit, Jariyanee, Putasaeng, Bundit, Moontragoon, Pairot, Srepusharawoot, Pornjuk, Thongbai, Prasit
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Elsevier 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9871223/
https://www.ncbi.nlm.nih.gov/pubmed/36704279
http://dx.doi.org/10.1016/j.heliyon.2023.e12946
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author Saengvong, Pariwat
Boonlakhorn, Jakkree
Jumpatam, Jutapol
Chanlek, Narong
Prasongkit, Jariyanee
Putasaeng, Bundit
Moontragoon, Pairot
Srepusharawoot, Pornjuk
Thongbai, Prasit
author_facet Saengvong, Pariwat
Boonlakhorn, Jakkree
Jumpatam, Jutapol
Chanlek, Narong
Prasongkit, Jariyanee
Putasaeng, Bundit
Moontragoon, Pairot
Srepusharawoot, Pornjuk
Thongbai, Prasit
author_sort Saengvong, Pariwat
collection PubMed
description The effects of sintering conditions on the microstructure, giant dielectric response, and electrical properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) (NYCTTaO) were studied. A single phase of Na(1/2)Y(1/2)Cu(3)Ti(4)O(12) and a high density (>98.5%) were obtained in the sintered NYCTTaO ceramics. First–principles calculations were used to study the structure of the NYCTTaO. Insulating grain boundaries (i–GBs) and semiconducting grains (semi–Gs) were studied at different temperatures using impedance and admittance spectroscopies. The conduction activation energies of the semi–Gs and i–GBs were E(g) ≈ 0.1 and E(gb) ≈ 0.6 eV, respectively. A large dielectric constant (ε′ ≈ 2.43–3.89 × 10(4)) and low loss tangent (tanδ ≈ 0.046–0.021) were achieved. When the sintering temperature was increased from 1070 to 1090 °C, the mean grain size slightly increased, while ε′ showed the opposite tendency. Furthermore, the breakdown electric field (E(b)) increases significantly. As the sintering time increased from 5 to 10 h, the mean grain size did not change, whereas ε′ and E(b) increased. Variations in the dielectric response and non–linear electrical properties were primarily described by the intrinsic (E(gb)) and extrinsic (segregation of Na–, Cu–, Ta–, and O–rich phases) properties of the i–GBs based on the internal barrier layer capacitor effect.
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spelling pubmed-98712232023-01-25 Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics Saengvong, Pariwat Boonlakhorn, Jakkree Jumpatam, Jutapol Chanlek, Narong Prasongkit, Jariyanee Putasaeng, Bundit Moontragoon, Pairot Srepusharawoot, Pornjuk Thongbai, Prasit Heliyon Research Article The effects of sintering conditions on the microstructure, giant dielectric response, and electrical properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) (NYCTTaO) were studied. A single phase of Na(1/2)Y(1/2)Cu(3)Ti(4)O(12) and a high density (>98.5%) were obtained in the sintered NYCTTaO ceramics. First–principles calculations were used to study the structure of the NYCTTaO. Insulating grain boundaries (i–GBs) and semiconducting grains (semi–Gs) were studied at different temperatures using impedance and admittance spectroscopies. The conduction activation energies of the semi–Gs and i–GBs were E(g) ≈ 0.1 and E(gb) ≈ 0.6 eV, respectively. A large dielectric constant (ε′ ≈ 2.43–3.89 × 10(4)) and low loss tangent (tanδ ≈ 0.046–0.021) were achieved. When the sintering temperature was increased from 1070 to 1090 °C, the mean grain size slightly increased, while ε′ showed the opposite tendency. Furthermore, the breakdown electric field (E(b)) increases significantly. As the sintering time increased from 5 to 10 h, the mean grain size did not change, whereas ε′ and E(b) increased. Variations in the dielectric response and non–linear electrical properties were primarily described by the intrinsic (E(gb)) and extrinsic (segregation of Na–, Cu–, Ta–, and O–rich phases) properties of the i–GBs based on the internal barrier layer capacitor effect. Elsevier 2023-01-14 /pmc/articles/PMC9871223/ /pubmed/36704279 http://dx.doi.org/10.1016/j.heliyon.2023.e12946 Text en © 2023 The Authors https://creativecommons.org/licenses/by-nc-nd/4.0/This is an open access article under the CC BY-NC-ND license (http://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Research Article
Saengvong, Pariwat
Boonlakhorn, Jakkree
Jumpatam, Jutapol
Chanlek, Narong
Prasongkit, Jariyanee
Putasaeng, Bundit
Moontragoon, Pairot
Srepusharawoot, Pornjuk
Thongbai, Prasit
Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title_full Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title_fullStr Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title_full_unstemmed Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title_short Effects of sintering condition on giant dielectric and nonlinear current-voltage properties of Na(1/2)Y(1/2)Cu(3)Ti(3.975)Ta(0.025)O(12) ceramics
title_sort effects of sintering condition on giant dielectric and nonlinear current-voltage properties of na(1/2)y(1/2)cu(3)ti(3.975)ta(0.025)o(12) ceramics
topic Research Article
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9871223/
https://www.ncbi.nlm.nih.gov/pubmed/36704279
http://dx.doi.org/10.1016/j.heliyon.2023.e12946
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