Cargando…

Iridium complexes of an ortho-trifluoromethylphenyl substituted PONOP pincer ligand

The synthesis and iridium coordination chemistry of a new pyridine-based phosphinito pincer ligand 2,6-(Ar(F)(2)PO)(2)C(5)H(3)N (PONOP-Ar(F); Ar(F) = 2-(CF(3))C(6)H(4)) are described, where the P-donors have ortho-trifluoromethylphenyl substituents. The iridium(iii) 2,2′-biphenyl (biph) derivative [...

Descripción completa

Detalles Bibliográficos
Autores principales:	Poole, Ethan W., Bustos, Itxaso, Hood, Thomas M., Smart, Jennifer E., Chaplin, Adrian B.
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	The Royal Society of Chemistry 2022
Materias:	Chemistry
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9872493/ https://www.ncbi.nlm.nih.gov/pubmed/36602231 http://dx.doi.org/10.1039/d2dt03608h

Ejemplares similares

Synthesis and Structural Dynamics of Five-Coordinate Rh(III) and Ir(III) PNP and PONOP Pincer Complexes
por: Hood, Thomas M., et al.
Publicado: (2019)

Oxidative Addition of C–Cl Bonds to a Rh(PONOP) Pincer Complex
por: Longcake, Alexandra, et al.
Publicado: (2022)

DFT calculations bring insight to internal alkyne-to-vinylidene transformations at rhodium PNP- and PONOP-pincer complexes
por: Rajabi, Nasir A., et al.
Publicado: (2021)

A convenient method for the generation of {Rh(PNP)}(+) and {Rh(PONOP)}(+) fragments: reversible formation of vinylidene derivatives
por: Gyton, Matthew R., et al.
Publicado: (2019)

Decarbonylative ether dissection by iridium pincer complexes
por: Yoo, Changho, et al.
Publicado: (2020)

A metal–organic framework immobilised iridium pincer complex
por: Rimoldi, Martino, et al.
Publicado: (2016)

A genuine germylene PGeP pincer ligand for formic acid dehydrogenation with iridium
por: Fernández-Buenestado, Marta, et al.
Publicado: (2023)

Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes
por: Lee, Chun-I, et al.
Publicado: (2015)

Electrochemical C–H bond activation via cationic iridium hydride pincer complexes
por: Lindley, Brian M., et al.
Publicado: (2019)

Correction: Ligand survey results in identification of PNP pincer complexes of iridium as long-lived and chemoselective catalysts for dehydrogenative borylation of terminal alkynes
por: Lee, Chun-I, et al.
Publicado: (2015)

Crystal structures of two PCN pincer iridium complexes and one PCP pincer carbodiphosphorane iridium intermediate: substitution of one phosphine moiety of a carbodiphosphorane by an organic azide
por: Partl, Gabriel Julian, et al.
Publicado: (2019)

Reversible addition of ethylene to a pincer-based boryl-iridium unit with the formation of a bridging ethylidene
por: Cao, Yihan, et al.
Publicado: (2020)

Formation of a C–C double bond from two aliphatic carbons. Multiple C–H activations in an iridium pincer complex
por: Polukeev, Alexey V., et al.
Publicado: (2015)

Ortho-aryl substituted DPEphos ligands: rhodium complexes featuring C–H anagostic interactions and B–H agostic bonds
por: Race, James J., et al.
Publicado: (2021)

Rhodium(I) Pincer Complexes of Nitrous Oxide
por: Gyton, Matthew R., et al.
Publicado: (2019)

Iridium-catalyzed ortho-selective carbon–hydrogen amidation of benzamides with sulfonyl azides in ionic liquid
por: Jiao, Lin-Yu, et al.
Publicado: (2020)

Structural diversity of halocarbonyl molybdenum and tungsten PNP pincer complexes through ligand modifications
por: de Aguiar, Sara R. M. M., et al.
Publicado: (2016)

Bimetallic iron–iron and iron–zinc complexes of the redox-active ONO pincer ligand
por: Wong, Janice L., et al.
Publicado: (2016)

Synthesis and cytotoxicity against tumor cells of pincer N-heterocyclic ligands and their transition metal complexes
por: Oulmidi, Afaf, et al.
Publicado: (2021)

Luminescent Iridium(III) Complexes Supported by N-Heterocyclic Carbene-based C^C^C-Pincer Ligands and Aromatic Diimines
por: Chung, Lai-Hon, et al.
Publicado: (2015)

Solvent-modulated proton-coupled electron transfer in an iridium complex with an ESIPT ligand
por: Kim, Siin, et al.
Publicado: (2022)

Probing the donor strength of yldiide ligands: synthesis, structure and reactivity of rhodium complexes with a PC(ylide)N pincer ligand
por: Lapointe, Sébastien, et al.
Publicado: (2023)

Applications of iron pincer complexes in hydrosilylation reactions
por: Nihala, Rasheed, et al.
Publicado: (2022)

Crystal structures of four new iridium complexes, each containing a highly flexible carbodiphosphorane PCP pincer ligand
por: Partl, Gabriel Julian, et al.
Publicado: (2018)

Crystal structure of an iridium(III) complex of the [C(dppm)(2)] PCP pincer ligand system and its conjugate CH acid form
por: Reitsamer, Christian, et al.
Publicado: (2018)

Transfer hydrogenation of aldehydes catalyzed by silyl hydrido iron complexes bearing a [PSiP] pincer ligand
por: Zhang, Peng, et al.
Publicado: (2018)

Hydration of nitriles using a metal–ligand cooperative ruthenium pincer catalyst
por: Guo, Beibei, et al.
Publicado: (2019)

Metal–Ligand Proton Tautomerism, Electron Transfer, and C(sp(3))–H Activation by a 4-Pyridinyl-Pincer Iridium Hydride Complex
por: Bhatti, Tariq M., et al.
Publicado: (2023)

η(2)-Alkene Complexes of [Rh(PONOP-(i)Pr)(L)](+) Cations (L = COD, NBD, Ethene). Intramolecular Alkene-Assisted Hydrogenation and Dihydrogen Complex [Rh(PONOP-(i)Pr)(η-H(2))](+)
por: Johnson, Alice, et al.
Publicado: (2021)

Ligand effect of cyclometallated iridium(iii) complexes on N-alkylation of amines in hydrogen borrowing reactions
por: Chen, Yi-Sheng, et al.
Publicado: (2023)

Pseudo-octahedral nickel(ii) complexes of strongly absorbing benzannulated pincer-type amido ligands: ligand-based redox and non-Aufbau electronic behaviour
por: Braun, Jason D., et al.
Publicado: (2021)

Immobilization of an Iridium Pincer Complex in a Microporous Polymer for Application in Room‐Temperature Gas Phase Catalysis
por: König, Michaela, et al.
Publicado: (2020)

Probing the Donor Properties of Pincer Ligands Using Rhodium Carbonyl Fragments: An Experimental and Computational Case Study
por: Parker, Gemma L., et al.
Publicado: (2019)

H/D exchange under mild conditions in arenes and unactivated alkanes with C(6)D(6) and D(2)O using rigid, electron-rich iridium PCP pincer complexes
por: Smith, Joel D., et al.
Publicado: (2020)

Sustainable catalysis with fluxional acridine-based PNP pincer complexes
por: Kar, Sayan, et al.
Publicado: (2022)

Highly efficient hydrogenation of carbon dioxide to formate catalyzed by iridium(iii) complexes of imine–diphosphine ligands
por: Liu, Chong, et al.
Publicado: (2015)

Iridium-catalyzed asymmetric hydrogenation of racemic α-substituted lactones to chiral diols
por: Yang, Xiao-Hui, et al.
Publicado: (2017)

Ligand-free iridium-catalyzed regioselective C–H borylation of indoles
por: Pan, Zilong, et al.
Publicado: (2021)

Synthesis and luminescence modulation of pyrazine-based gold(iii) pincer complexes
por: Fernandez-Cestau, Julio, et al.
Publicado: (2015)

Halide exchange studies of novel Pd(ii) NNN-pincer complexes
por: Kuyuldar, Seher, et al.
Publicado: (2019)

Cannot write session to /tmp/vufind_sessions/sess_82vrd7boonhadcj86nh0j0qkge