Cargando…

Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites

Modifying biodegradable poly (butylene adipate-co-terephthalate) (PBAT) plastic with inorganic fillers is critical for improving its overall performance, lowering the costs, and expanding its application scope. The chemical modification method for the inorganic filler determines the application perf...

Descripción completa

Detalles Bibliográficos
Autores principales: Shang, Jinzhi, Li, Chang, Song, Yang, Yan, Mingkai, Li, Lin, Hu, Chaoquan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Frontiers Media S.A. 2023
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9877299/
https://www.ncbi.nlm.nih.gov/pubmed/36712983
http://dx.doi.org/10.3389/fchem.2022.1119978
_version_ 1784878335822659584
author Shang, Jinzhi
Li, Chang
Song, Yang
Yan, Mingkai
Li, Lin
Hu, Chaoquan
author_facet Shang, Jinzhi
Li, Chang
Song, Yang
Yan, Mingkai
Li, Lin
Hu, Chaoquan
author_sort Shang, Jinzhi
collection PubMed
description Modifying biodegradable poly (butylene adipate-co-terephthalate) (PBAT) plastic with inorganic fillers is critical for improving its overall performance, lowering the costs, and expanding its application scope. The chemical modification method for the inorganic filler determines the application performance of PBAT composites. In this work, gas—solid fluidization method was developed as a simple, efficient, and scalable strategy for chemically modifying CaCO(3) filler. The modified CaCO(3) filler was mixed with PBAT and melt extruded to prepare biodegradable PBAT/CaCO(3) composites. The characterization results show that gas—solid fluidization method combines the traditional wet modification method’s excellent modification effect with the scalability of the traditional dry modification method. The effects of modification methods and amount of CaCO(3) filling on the crystallinity, mechanical, and rheological properties of PBAT/CaCO(3) composites were compared. The results demonstrated that PBAT/CaCO(3) composites containing 30% gas—solid fluidization modified CaCO(3) could still maintain excellent overall performance. As a result, this work provides a simple, efficient, and scalable method for chemically modifying inorganic fillers and preparing biodegradable composites.
format Online
Article
Text
id pubmed-9877299
institution National Center for Biotechnology Information
language English
publishDate 2023
publisher Frontiers Media S.A.
record_format MEDLINE/PubMed
spelling pubmed-98772992023-01-27 Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites Shang, Jinzhi Li, Chang Song, Yang Yan, Mingkai Li, Lin Hu, Chaoquan Front Chem Chemistry Modifying biodegradable poly (butylene adipate-co-terephthalate) (PBAT) plastic with inorganic fillers is critical for improving its overall performance, lowering the costs, and expanding its application scope. The chemical modification method for the inorganic filler determines the application performance of PBAT composites. In this work, gas—solid fluidization method was developed as a simple, efficient, and scalable strategy for chemically modifying CaCO(3) filler. The modified CaCO(3) filler was mixed with PBAT and melt extruded to prepare biodegradable PBAT/CaCO(3) composites. The characterization results show that gas—solid fluidization method combines the traditional wet modification method’s excellent modification effect with the scalability of the traditional dry modification method. The effects of modification methods and amount of CaCO(3) filling on the crystallinity, mechanical, and rheological properties of PBAT/CaCO(3) composites were compared. The results demonstrated that PBAT/CaCO(3) composites containing 30% gas—solid fluidization modified CaCO(3) could still maintain excellent overall performance. As a result, this work provides a simple, efficient, and scalable method for chemically modifying inorganic fillers and preparing biodegradable composites. Frontiers Media S.A. 2023-01-12 /pmc/articles/PMC9877299/ /pubmed/36712983 http://dx.doi.org/10.3389/fchem.2022.1119978 Text en Copyright © 2023 Shang, Li, Song, Yan, Li and Hu. https://creativecommons.org/licenses/by/4.0/This is an open-access article distributed under the terms of the Creative Commons Attribution License (CC BY). The use, distribution or reproduction in other forums is permitted, provided the original author(s) and the copyright owner(s) are credited and that the original publication in this journal is cited, in accordance with accepted academic practice. No use, distribution or reproduction is permitted which does not comply with these terms.
spellingShingle Chemistry
Shang, Jinzhi
Li, Chang
Song, Yang
Yan, Mingkai
Li, Lin
Hu, Chaoquan
Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title_full Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title_fullStr Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title_full_unstemmed Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title_short Gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (PBAT) composites
title_sort gas-solid fluidization modification of calcium carbonate for high-performance poly (butylene adipate-co-terephthalate) (pbat) composites
topic Chemistry
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9877299/
https://www.ncbi.nlm.nih.gov/pubmed/36712983
http://dx.doi.org/10.3389/fchem.2022.1119978
work_keys_str_mv AT shangjinzhi gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites
AT lichang gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites
AT songyang gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites
AT yanmingkai gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites
AT lilin gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites
AT huchaoquan gassolidfluidizationmodificationofcalciumcarbonateforhighperformancepolybutyleneadipatecoterephthalatepbatcomposites