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Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution

[Image: see text] The inhibitory capabilities of the sweet yellow capsicum extract (SYCE) toward the rusting of steel rebars in cement pore solution (CPS) were tested employing the electrochemical and mass loss methods. Gallic acid, caffeic acid, p-coumaric acid, ferulic acid, luteolin, and cinnamic...

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Autores principales: Deyab, Mohamed A., Mohsen, Q.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2023
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9878660/
https://www.ncbi.nlm.nih.gov/pubmed/36713737
http://dx.doi.org/10.1021/acsomega.2c06639
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author Deyab, Mohamed A.
Mohsen, Q.
author_facet Deyab, Mohamed A.
Mohsen, Q.
author_sort Deyab, Mohamed A.
collection PubMed
description [Image: see text] The inhibitory capabilities of the sweet yellow capsicum extract (SYCE) toward the rusting of steel rebars in cement pore solution (CPS) were tested employing the electrochemical and mass loss methods. Gallic acid, caffeic acid, p-coumaric acid, ferulic acid, luteolin, and cinnamic acid are the most important constituents in the SYCE extract. By adsorbing them on steel bars, the organic compounds in the CSA extract enable them with an effective mixed-type inhibition, suppressing both anodic and cathodic procedures. At 300 ppm, the highest performances were 95.3 and 97.5% utilizing mass loss and electrochemical approaches, respectively. The activation energy for the corrosion process is greatly increased by the addition of the SYCE extract, going from 13.2 kJ mol(–1) (blank solution) to 30.0 kJ mol(–1) (300 ppm SYCE extract). The physical adsorption actions of the SYCE extract are described by the Freundlich equilibrium constant’s smallest value, which is 0.074 ppm(–1). Many future investigators will be attracted by these discoveries to work relentlessly to uncover the anti-corrosion characteristics of novel plant extracts in the area of concrete additives.
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spelling pubmed-98786602023-01-27 Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution Deyab, Mohamed A. Mohsen, Q. ACS Omega [Image: see text] The inhibitory capabilities of the sweet yellow capsicum extract (SYCE) toward the rusting of steel rebars in cement pore solution (CPS) were tested employing the electrochemical and mass loss methods. Gallic acid, caffeic acid, p-coumaric acid, ferulic acid, luteolin, and cinnamic acid are the most important constituents in the SYCE extract. By adsorbing them on steel bars, the organic compounds in the CSA extract enable them with an effective mixed-type inhibition, suppressing both anodic and cathodic procedures. At 300 ppm, the highest performances were 95.3 and 97.5% utilizing mass loss and electrochemical approaches, respectively. The activation energy for the corrosion process is greatly increased by the addition of the SYCE extract, going from 13.2 kJ mol(–1) (blank solution) to 30.0 kJ mol(–1) (300 ppm SYCE extract). The physical adsorption actions of the SYCE extract are described by the Freundlich equilibrium constant’s smallest value, which is 0.074 ppm(–1). Many future investigators will be attracted by these discoveries to work relentlessly to uncover the anti-corrosion characteristics of novel plant extracts in the area of concrete additives. American Chemical Society 2023-01-09 /pmc/articles/PMC9878660/ /pubmed/36713737 http://dx.doi.org/10.1021/acsomega.2c06639 Text en © 2023 The Authors. Published by American Chemical Society https://creativecommons.org/licenses/by-nc-nd/4.0/Permits non-commercial access and re-use, provided that author attribution and integrity are maintained; but does not permit creation of adaptations or other derivative works (https://creativecommons.org/licenses/by-nc-nd/4.0/).
spellingShingle Deyab, Mohamed A.
Mohsen, Q.
Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title_full Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title_fullStr Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title_full_unstemmed Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title_short Inhibitory Capabilities of Sweet Yellow Capsicum Extract toward the Rusting of Steel Rebars in Cement Pore Solution
title_sort inhibitory capabilities of sweet yellow capsicum extract toward the rusting of steel rebars in cement pore solution
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC9878660/
https://www.ncbi.nlm.nih.gov/pubmed/36713737
http://dx.doi.org/10.1021/acsomega.2c06639
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